Distinct coordination geometries in bis­[N,N-bis­(2-meth­oxy­eth­yl)di­thio­carbamato-κ2S,S′]di­phenyltin(IV) and bis­[N-(2-meth­oxy­eth­yl)-N-methyl­dithio­carbamato-κ2S,S′]di­phenyl­tin(IV): crystal structures and Hirshfeld surface analysis

Mohamad, R.; Awang, N.; Jotani, M.M.; Tiekink, E.R.T.

doi:10.1107/S2056989016011385

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 8
View of the Hirshfeld surfaces for (I)

, showing (a) mapped over d_e with the pale-orange spot within the blue circle indicating the involvement of the aryl ring in C—H⋯π interactions and (b) mapped with the shape-index property with the bright-red spot, identified with an arrow, indicating the C—H⋯π interaction and the blue spots indicating complementary π⋯H—C interactions.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 72| Part 8| August 2016| Pages 1130-1137

https://doi.org/10.1107/S2056989016011385

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