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Figure 1
The different coordination modes in the M(pds)(nab)2 family. (I): {[Cd(pds)(Bpy)2}n, P[\overline{1}] (Harvey et al., 2001aBB4); (II): {[Hg(pds)(Bpy)2}n, P21/n (Díaz de Vivar et al., 2005BB1); (III): Cd(pds)(Phen)2(H2O) P[\overline{1}] (Harvey et al., 2001bBB5); (IV): Zn(pds)(Phen)2(H2O), P[\overline{1}] (Harvey et al., 2011BB6); (V)[link]: Cd(pds)(DMPhen)2, C2/c (Harvey et al., 2001bBB5; Marsh, 2004BB9, and this work); (VI)[link]: Zn(pds)(TMPhen)2, P[\overline{1}] (this work); (VII)[link]: Cd(pds)(TMPhen)2, Pbcn (this work). Ligand code: Bpy = 2,2′-bi­pyridine; Phen = 1,10-phenanthroline, DMPhen = 2,9-dimethyl-1,10-phenanthroline, TMPhen = 3,4,7,8-tetra­methyl-1,10-phenanthroline.

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ISSN: 2056-9890
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