An unexpected oxidation: NaK5Cl2(S2O6)2 revisited

Harrison, W.T.A.; Plater, M.J.

doi:10.1107/S2056989017000494

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

IUCr IT WDC

home archive editors for authors for readers submit open access

view article

Figure 3
View down [001] of a slice (0.25 ≤ z ≤ 0.35) of the structure of (I). Displacement ellipsoids are displayed at the 50% probability level. [Symmetry codes: (iii) 1 − x, 1 − y, 1 − z; (iv) $[{3\over 2}]$ − y, x, z; (v) $[{1\over 2}]$ − y, x, z; (vi) $[{1\over 2}]$ + y, 1 − x, 1 − z; (vii) $[{1\over 2}]$ + x, $[{1\over 2}]$ + y, 1 − z.] Note that Cl1 and Cl2 lie on fourfold axes and Cl3 lies on a twofold axis. The chloride ions link to the sodium and potassium ions shown in Figs. 1