A new example of intra­molecular C—H⋯Ni anagostic inter­actions: synthesis, crystal structure and Hirshfeld analysis of cis-bis­[4-methyl-2-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)hydrazinecarbo­thio­amidato-κ2N1,S]nickel(II) di­methyl­formamide monosolvate

Oliveira, A.B. de; Beck, J.; Mellone, S.E.B.S.; Daniels, J.

doi:10.1107/S2056989017007198

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 4
Graphical representation of the two-dimensional Hirshfeld surface fingerprint plots for the interactions in the crystal structure of the title compound. The contacts are drawn in detail (cyan dots) and the contributions to the crystal packing amount to: (a) H⋯H = 66.6%, (b) H⋯S = 12.3%, (c) H⋯C = 10.9%, (d) H⋯N = 4.5%, (e) H⋯O = 4.0% and (f) H⋯Ni = 0.2%. The d_e (y axis) and d_i (x axis) values are the closest external and internal distances (values in Å) from given points on the Hirshfeld surface contacts.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 73| Part 6| June 2017| Pages 859-863

https://doi.org/10.1107/S2056989017007198

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