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Figure 2
A comparison of the observed conformers for the title compound, viewed down the Cl—Sn—O axis (top: the previously known polymorph; bottom: the new P21 polymorph). Note the different orientations observed for the apical DMSO mol­ecule. The calculated powder patterns displayed on the right show that both polymorphs are crystallographically very different. Patterns were calculated with Mercury (Macrae et al., 2008BB5; 5 < 2θ < 40°, λ = 1.54056 Å, FWHM = 0.2°).

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890
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