issue contents
November 1996 issue
inorganic compounds
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(NH4)3(PO2NH)3.H2O contains trimetaphosphimate anions, ammonium cations and water molecules linked by N—H⋯O and O-H⋯O hydrogen bonds.
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The superstructure of C-type Cr(PO3)3 has been refined from single-crystal data. The CrO6 octahedra are only slightly distorted and the PO4 tetrahedra show typical geometry for metaphosphate chains.
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The Fe atom in [Fe(CO)4(P4O6)] has trigonal-bipyramidal coordination geometry and the axial P4O6 unit shows distortions similar to those observed within the series P4O6X (X = O, S, Se).
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The structure of GdRh2B2C consists of tetrahedrally coordinated Rh2B2 layers and GdC NaCl-type layers which stack alternately along [001] via short B-C bonds.
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The structure of the [{Er3O(OH)3(H2O)3}2Al2(Nb6O19)5]26- anion is compared with that within the isomorphous Eu complex. The smaller ionic radius of Er3+ induces a contraction of the central [{Ln3O(OH)3(H2O)3}2]8+ cluster with a resultant attraction of the five [Nb6O19]8− groups towards the anion centre.
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The crystal structure of Be(H4IO6)2.4H2O has been established by single-crystal X-ray methods. Two of the H atoms within the [H4IO6]− anion are disordered over split positions.
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This new potassium beryllium silicate resulted from a high temperature and high pressure synthesis. It has a framework structure built from trimers of silicate tetrahedra and edge-sharing Be-O tetrahedra, and possesses one-dimensional channels along the b axis.
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The structure of H2SO4 consists of H2SO4 molecules connected by hydrogen bonds to form 44 nets. In (H3O)(HSO4), hydrogen bonding results in the formation of double layers consisting of (HSO4)n chains linked by (H3O) ions.
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(NH4)2(VO)(VP)O7 contains [(VO)(VP)O7]∞ layers consisting of divanadophosphate VPO7 groups and VO5 square pyramids, and layers of NH4+ ions.
metal-organic compounds
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organic compounds
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