High-temperature synthesis of Rb₂MnP₂S₆ in molten salt medium

Rubidium manganese hexa­thio­diphosphate, Rb₂MnP₂S₆, crystallizes in a structure typical of compounds of the type A₂MP₂Q₆ (A = K, Rb, Cs; M = Mn, Fe; Q = S, Se). Its structure can be viewed as columns of [MnP₂S₆]²⁻ polyhedra parallel to the a axis, interconnected by Rb⁺.

Barium tetraphosphate

The structure of the low-temperature form of barium tetraphosphate shows the tetraphosphate to exist in an S conformation.

A tetragonal polymorph of caesium hydroxide monohydrate, CsOH·H₂O, from X-ray powder data

The tetragonal polymorph of caesium hydro­xide monohydrate, CsOH·H₂O (or CsH₃O₂), a clathrate hydrate, contains an infinite three-dimensional hydrogen-bonded oxy­gen framework that is locally identical to layers found in the hexagonal modification.

Strontium manganese diselenite, SrMn(SeO₃)₂, containing unusual MnO₅₊₁ polyhedra

SrMn(SeO₃)₂ is built up from sheets of irregular MnO₅₊₁ units and pyramidal SeO₃ groups, sharing vertices and edges. Nine-coordinate Sr²⁺ cations complete the structure.

HgWO₄ synthesized at high pressure and temperature

The structure of HgWO₄ consists of zigzag chains of edge-sharing WO₆ octahedra running along the c axis and layers of corner-sharing HgO₆ octahedra in the bc plane.

Hg₃AlF₆O₂H, a structure with a short interpolyhedral O⋯O distance

The crystal structure of Hg₃AlF₆O₂H has been determined at room temperature. It comprises [HgO₂F₆] polyhedra and [AlF₆] octahedra. Assumed hydrogen bonding between two O atoms, with O⋯O = 2.562 (9) Å, provides additional bonds in the framework.

Synchrotron X-ray study of ortho­rhombic Rb₃Ta₅O₁₄ with a modified pyrochlore structure

The structure of a new variant orthorhombic Rb₃Ta₅O₁₄ phase with Pnma symmetry was identified from a half sphere of synchrotron X-ray data measured at a wavelength of 0.85 Å.

Chlorohepta­kis­(di­methyl sulfoxide)­uranium(IV) trichloride

Pseudosymmetry in pyridinium tetra­chloro(oxo)pyridineniobate(V) pyridine solvate

A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate

Bis(8-quinolinolato-N,O)platinum(II) and its synthetic intermediate, 8-hydroxyquinolinium di­chloro(8-quinolinolato-N,O)platinate(II) tetrahydrate

The sodium salt of 2-hy­droxy-5-nitro­benzylsulfonic acid

Interpenetrating nets in cis-bis­(pyri­dine-4-carboxyl­ate)­nickel(II)

Aqua­chloro(1,10-phenanthroline-κ²N,N′)(p-toluene­sulfonato-κO)copper(II)

Tri­chloro(1,1-di­methylbiguanidium-κN³)zinc(II)

Chloro­bis­(tri­phenyl­phosphine)­nickel(I)

Bis[1,1′-bis­(di­phenylphosphino)ferrocenium] hexadeca­chloro­tetraantimony(III) ethanol solvate

A pseudo-cage complex of silver(I) with tripodal tetra­amine having benzyl end groups, {tris­[2-(benzylamino)ethyl]amine-κ⁴N}silver(I) perchlorate

Three different bonding modes of cyano groups in the coordination polymer [Cu(en)₂(H₂O)][Cu(en)₂Ni₂Cu₂(CN)₁₀]·2H₂O (en is 1,2-di­aminoethane)

Deca­carbonylbis(methylcyclo­pentadienyl)-tetrahedro-diiridiumdimolybdenum and deca­carbonylbis(tetramethylcyclo­pentadienyl)-tetrahedro-diiridiumdimolybdenum di­chloro­methane hemisolvate

catena-Poly[[di-μ-chloro-bis­[(tri­phenylphosphine)silver(I)]]-μ-2-aminopyrimidine-κ²N¹:N³]

The trigonal–bipyramidal tri­iodo­thallium(III) complex [TlI₃{(CH₃)₂SO}₂]

Aqua[bis­(pyrimidin-2-yl-κN)amine](carbonato-κ²O,O′)copper(II) dihydrate

A copper(II)–pyrazole complex cation with imposed symmetry

Tris(1-ethyl-3-methyl­imidazolium) hexa­chloro­lanthanate

Tetra­kis­[(4-aminopyridinio)acetato-κO]di­aquamanganese(II) diper­chlorate

catena-Poly[[bis­(nicotinamide-κN¹)copper(I)]-μ-thio­cyanato-κ²N:S]

Three heterotrinuclear Schiff base complexes of nickel(II) with cobalt(II), copper(II) and manganese(II)

catena-Poly[bis­[tetra­aquacobalt(II)-μ-4,4′-bi­pyridine-κ²N:N′] benzene-1,2,4,5-tetra­carboxylate(4−) dihydrate]

The binary adduct of 3,6,9,16,19,22-hexa­azatri­cyclo[22.2.2.2^11,14]triaconta-11,13,24,26(1),27,29-hexa­ene and benzene-1,2,4,5-tetra­carboxylic acid

Stigmasterol hemihydrate

3,4-Di­hydro-6-methyl-3-β-D-ribo­furan­osyl-4,5′-cyclo-9H-imidazo[1,2-a]­purin-9-one hydrate

Piperazine-1,4-diium–2,4-di­nitrophenolate–water (1/2/2)

Ethyl 2-{[2-(3-nitro­phenyl)-5-phenyl-1H-imidazol-4-yl]­sulfanyl}acetate: synthesis via a microwave-mediated combinatorial chemistry approach

The α-D anomer of 5-aza-7-de­aza-2′-deoxyguanosine

[4-(Tri­fluoro­methyl)­phenyl]­aceto­nitrile

1-Methyl-5,6,7,8-tetra­hydro­quin­oxalin-2(1H)-one

Flat versus twisted rotamers of 2,4-disubstituted thiazoles: the effect of intermolecular hydrogen bonds

()-3-Oxo­cyclo­hexane­carboxylic and -acetic acids: contrasting hydrogen-bonding patterns in two homologous keto acids

2-Methylphenyl 2-methoxyacridine-9-carboxylate

trans-3-Ethyl-cis-2,6,6-tri­methyl-4-oxo­cyclo­hexane­carboxylic acid: an intermediate in the synthesis of a highly potent estrogen

4-(3,17-Dioxoandrost-4-en-16-yl­idene­methyl)benzo­nitrile

Three tetra­hydroiso­quinolinedione derivatives

5-Butyl-4-(4,4,5,5-tetra­methyl-1,3,2-dioxaborolan-2-yl)-3-(2,4,6-tri­methyl­phenyl)­isoxazole

Steroid 19,B-dinor-8,10-iso-analogues

D-Secoestrone derivatives. VI. 17β-Benzyl-17α-hy­droxy-3-meth­oxyestra-1,3,5(10)-trien-16-one

4-Amino derivatives of 7-nitro-2,1,3-benzoxa­diazole: the effect of the amino moiety on the structure of fluorophores

The diastereoisomers methyl 5-(S)-[2-(R)/(S)-methoxycarbonyl)-2,3,4,5-tetra­hydropyrrol-1-ylcarbonyl]-1-(4-methylphenyl)-4,5-di­hydro­pyrazole-3-carboxylate

The β-polymorph of phenazine

Di­spiro­[2H-benz­imidazole-2,1′-cyclo­hexane-4′,2′′-[2H]­benz­imidazole] 1-oxide and di­spiro[2H-benzimid­azole-2,1′-cyclo­hexane-4′,2′′-[2H]benzimidazole] 1,1′′-dioxide

Cyclo­hexylphosphonic acid

Tetra­kis­(chloro­methyl)phosphonium chloride monohydrate

1,3-Di­methyl-2-oxo-4,6-di­phenyl-1,2,3,4-tetra­hydro­pyridine-3-carbonitrile

1,3-Bis(2,4-di­bromo­phenyl)triazene

Three ginkgolide hydrates from Ginkgo biloba L.: ginkgolide A monohydrate, ginkgolide C sesquihydrate and ginkgolide J dihydrate, all determined at 120 K

The anti-inflammatory triterpenoid methyl 2-cyano-3,12-dioxooleana-1,9(11)-dien-28-oate methanol solvate hydrate