issue contents
August 2002 issue
inorganic compounds
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Rb(GaPO4)2(OH)(H2O)·H2O exhibits a three-dimensional framework with intersecting eight-ring channels, in which the alkali cations and the water molecule are encapsulated. This network belongs to the leucophosphite structural type.
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The title compounds are isotypic. KMo5O13 has a three-dimensional tunnel built by the corner-sharing of MoO6 octahedra; K+ cations are located in the tunnels. In KNb1.76Sb3.24O13, the Nb and Sb atoms occupy the same sites.
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Fe7(PO4)2(HPO4)4 is isostructural with Mn7(PO4)2(HPO4)4 and Co7(PO4)2(HPO4)4. The structure is based on a framework of edge- and corner-sharing FeO6, Fe5 and PO4 polyhedra, isotypic with that found in the mixed-valence iron phosphate Fe7(PO4)6. The Fe atoms are purely in the divalent state, just like the Co atoms in Co7(PO4)2(HPO4)4, the necessary charge balance being maintained by the addition of H atoms in the form of bridging Fe—OH—P groups.
metal-organic compounds
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organic compounds
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