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March 2009 issue
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Cover illustration: Hydrogen-bonding in the discrete cyclic centrosymmetric bis(cation-anion) `heterotetramer' structural units in 2-aminopyrimidinium 2-carboxy-4,5-dichlorobenzoate, shown as dashed lines. Non-interacting H atoms have been omitted. See Smith, Wermuth & White [Acta Cryst. (2009), C65, o103-o107].
inorganic compounds
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The title intermetallic compounds crystallize in the tetragonal Mo2FeB2-type structure. All three crystallographically unique atoms occupy special positions and the site symmetries of (Sc/Y, Ga) and Mg are m2m and 4/m, respectively. The coordinations around Sc/Y, Mg and Ga are pentagonal (Sc/Y), tetragonal (Mg) and triangular (Ga) prisms, with four (Mg) or three (Ga) additional capping atoms leading to the coordination numbers [10], [8+4] and [6+3], respectively. The crystal structure of Sc2MgGa2 was determined from single-crystal diffraction intensities and the isostructural Y2MgGa2 was identified from powder diffraction data.
metal-organic compounds
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organic compounds
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addenda and errata
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