issue contents
June 2010 issue
inorganic compounds
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The title compound contains infinite chains built up from V(H2O)2O4 octahedra and SeO3 pyramids. A network of O—H⋯O hydrogen bonds helps to consolidate the packing.
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β-Zn3(AsO3)2 contains unusual edge-sharing ZnO4 tetrahedra as part of its three-dimensional array of ZnO4 and AsO3 units. It is a polymorph of the mineral reinerite, which also contains edge-shared ZnO4 tetrahedra.
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Ag2.54Tl2Mo12Se15 constitutes a new structure type containing Mo6 and Mo9 clusters. Contrary to the previous mixed Mo6/Mo9 cluster compounds in which the cluster ratio is 1:1, in the title compound the Mo6 and Mo9 clusters are in a 1:2 ratio.
metal-organic compounds
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organic compounds
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