K₂[Hg(SO₃)₂]·2.25H₂O

The crystal structure of K₂[Hg(SO₃)₂]·2.25H₂O contains two S-bonded sulfitomercurate anions, [Hg(SO₃)₂]²⁻, which are arranged pairwise and are surrounded by two K⁺ cations to give an anionic {K₂[Hg(SO₃)₂]₂}²⁻ layer. The inter­layer space is filled with the remaining cations and the water mol­ecules.

Mg₅TiO₄(BO₃)₂

Mg₅TiO₄(BO₃)₂ crystallizes in an ortho­rhom­bic cell with the space group Pbam. It is isostructural with the mineral ludwigite (Mg₂FeO₂BO₃).

The novel arsenate Na₄Co_7−xAl_2/3x(AsO₄)₆ (x = 1.37): crystal structure, charge-distribution and bond-valence-sum investigations

The title mixed hexaarsenate, Na₄Co_5.63Al_0.91(AsO₄)₆, features a centrosymmetric three-dimensional framework composed of Co- and (Co,Al)-centred polyhedra and As-centred tetrahedra with tunnels running along [100] occupied by Na⁺ cations. Charge-distribution and bond-valence-sum calculations were used to support the structural model, and the experimental and validation results are discussed.

A new [(1R,2R)-1,2-di­amino­cyclo­hexane]platinum(II) complex: formation by nitrate–aceto­nitrile ligand exchange

catena-Poly[thorium(IV)-tetra­kis­(μ₂-3-carb­oxy­adamantane-1-carboxyl­ato)]: a quadruple helical strand driven by a synergy of coordination and hydrogen bonding

Bis{μ-2-[(2-carbamoylhydrazin-1-yl­idene)methyl]phenolato}bis­[chlorido­zinc(II)] methanol disolvate, with non-aromatic–aromatic π–π stacking and N—H⋯Cl—Zn hydrogen bonding

A two-dimensional Zn^II coordination polymer constructed by benzo­triazole-5-carboxyl­ate and 1,4,8,9-tetra­aza­tri­phenyl­ene

A new coordination complex based on a polynitrile ligand: bis­(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)di­aqua­iron(II) bis­(1,1,3,3-tetra­cyano-2-methyl­sulfanylpropenide)

An optically pure P–alkene-ligated Ir^I complex

A urea adduct of bis­(hinokitiolato)­copper(II)

The first square-planar copper(II) 1:2 complex with differently coordinated 2-hy­droxy­benzaldehyde 4-allyl­thio­semicarbazone ligands

A low-temperature phase of bis­(tetra­butyl­ammonium) octa-μ₃-chlorido-hexa­chlorido-octa­hedro-hexa­tungstate

(Acetato-κ²O,O′)di­hydroxido­ytterbium(III) hemihydrate

Poly[(μ₄-bi­phenyl-3,3′,4,4′-tetra­carboxyl­ato)bis­[μ₂-1,4-bis­(imidazol-1-ylmeth­yl)benzene]­dicobalt(II)]

Structural properties of trans-cyclo­hexane-1,2-di­amine complexes of copper(II) and zinc(II) acesulfamates

Two isomorphous aza­stilbene derivatives: 1-(2-chloro­benz­yl)-4-[(E)-2-(4-hy­droxy­phenyl)ethenyl]pyridinium chloride and 1-(2-bromo­benzyl)-4-[(E)-2-(4-hy­droxy­phenyl)­ethenyl]­pyridinium bromide

4-De­oxy-4-fluoro-β-D-gluco­pyranose

6-[(4-Fluoro­phenyl)(1H-imidazol-1-yl)methyl]-1,3-benzodioxol-5-ol and 6-[(4-meth­oxy­phenyl)(1H-imidazol-1-yl)methyl]-1,3-benzodioxol-5-ol

7-Amino-2-methyl­sulfanyl-1,2,4-tri­azolo[1,5-a]pyrimidine-6-carb­oxy­lic acid as the di­methyl­formamide and water monosolvates at 293 K

Two three-dimensional networks in two polymorphs of bi­phenyl-4,4′-diaminium bis­(3-carb­oxy-4-hy­droxy­benzene­sulfonate) dihydrate

Unconventional hydrogen bonding and π-stacking in two substituted pyridine carboxamides

6,6′-Dimeth­oxy­gossypolone

2-Cyano-N-(4,6-dimeth­oxy­pyrimidin-2-yl)acetamide: complex sheets built from N—H⋯O and C—H⋯O hydrogen bonds

N,N-Di­phenyl­benzamide