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October 2010 issue
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Cover illustration: A projection of the structure of catena-poly[thorium(IV)-tetrakis(2-3-carboxyadamantane-1-carboxylato)] on the ab plane, showing the packing of the coordination chains. C-H
O hydrogen bonds have been omitted for clarity. See Nazarenko, Rusanova, Krautscheid & Domasevitch [Acta Cryst. (2010), C66, m276-m279].
inorganic compounds
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The crystal structure of K2[Hg(SO3)2]·2.25H2O contains two S-bonded sulfitomercurate anions, [Hg(SO3)2]2−, which are arranged pairwise and are surrounded by two K+ cations to give an anionic {K2[Hg(SO3)2]2}2− layer. The interlayer space is filled with the remaining cations and the water molecules.
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Mg5TiO4(BO3)2 crystallizes in an orthorhombic cell with the space group Pbam. It is isostructural with the mineral ludwigite (Mg2FeO2BO3).
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The title mixed hexaarsenate, Na4Co5.63Al0.91(AsO4)6, features a centrosymmetric three-dimensional framework composed of Co- and (Co,Al)-centred polyhedra and As-centred tetrahedra with tunnels running along [100] occupied by Na+ cations. Charge-distribution and bond-valence-sum calculations were used to support the structural model, and the experimental and validation results are discussed.
metal-organic compounds
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organic compounds
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