Diaqua­bis(5-bromo-2-hydroxy­benzoato)bis­(N-methyl­nicotinamide)zinc(II)

Bujdošová, Z.; Kuchár, J.; Györyová, K.

doi:10.1107/S1600536810008834

metal-organic compounds

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 66| Part 4| April 2010| Pages m394-m395

doi:10.1107/S1600536810008834

Open

access

Diaquabis(5-bromo-2-hydroxybenzoato)bis(N-methylnicotinamide)zinc(II)

Zuzana Bujdošová,^a ^* Juraj Kuchár ^a and Katarína Györyová ^a

^aDepartment of Inorganic Chemistry, Institute of Chemistry, P. J. Šafárik University, Moyzesova 11, 041 54 Košice, Slovakia
^*Correspondence e-mail: zuzana.bujdosova@upjs.sk

(Received 26 February 2010; accepted 8 March 2010; online 13 March 2010)

The title mononuclear complex molecule, [Zn(C₇H₄BrO₃)₂(C₇H₈N₂O)₂(H₂O)₂], has a crystallographically imposed centre of symmetry. The zinc(II) atom is coordinated by two N atoms from two N-methylnicotinamide ligands, two O atoms from two 5-bromosalicylate anions and two aqua O atoms in a slightly distorted octahedral geometry. Intramolecular O—H⋯O hydrogen-bonding interactions are present. In the crystal structure, molecules are linked by intermolecular O—H⋯O and N—H⋯O hydrogen bonds, forming a two-dimensional network perpendicular to [100].

Related literature

For general background to the properties of carboxylic acid–metal complexes, see: Nagar (1990 ); Cavagiolio et al. (2000 ). For the synthesis and properties of zinc(II) carboxylates reported by our group, see: Györyová et al. (2005 , 2006 ); Bujdošová et al. (2009 ); Gebicki et al. (2003 ). For related structures, see: Necefoglu et al. (2001a ,b ); Hökelek et al. (2007 , 2009a ,b ); Öztürk et al. (2008 ); Sarı et al. (2007 ); Liu et al. (2004 ).

Experimental

Crystal data

[Zn(C₇H₄BrO₃)₂(C₇H₈N₂O)₂(H₂O)₂]
M_r = 805.73
Triclinic, $[P \overline 1]$
a = 8.1600 (2) Å
b = 10.1122 (3) Å
c = 10.4291 (3) Å
α = 66.800 (3)°
β = 74.334 (2)°
γ = 80.743 (2)°
V = 760.15 (4) Å³
Z = 1
Mo Kα radiation
μ = 3.50 mm⁻¹
T = 290 K
0.57 × 0.30 × 0.26 mm

Data collection

Oxford Diffraction Xcalibur Sapphire2 diffractometer
Absorption correction: numerical [Clark & Reid (1995 ) in CrysAlis PRO (Oxford Diffraction, 2009 $[Oxford Diffraction (2009). CrysAlis PRO. Oxford Diffraction Ltd, Yarnton, England.]$ )] T_min = 0.289, T_max = 0.484
32240 measured reflections
3153 independent reflections
2686 reflections with I > 2σ(I)
R_int = 0.024

Refinement

R[F² > 2σ(F²)] = 0.022
wR(F²) = 0.064
S = 1.15
3153 reflections
195 parameters
H-atom parameters constrained
Δρ_max = 0.50 e Å⁻³
Δρ_min = −0.49 e Å⁻³

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O3—H1O3⋯O2	0.82	1.81	2.540 (2)	147
N2—H1N2⋯O3ⁱ	0.86	2.55	3.1109 (19)	123
O5—H2O5⋯O2ⁱⁱ	0.82	1.88	2.6694 (18)	162
O5—H1O5⋯O4ⁱⁱⁱ	0.82	1.94	2.7568 (13)	179
Symmetry codes: (i) x, y, z+1; (ii) -x+1, -y, -z; (iii) x, y-1, z.

Data collection: CrysAlis PRO (Oxford Diffraction, 2009 $[Oxford Diffraction (2009). CrysAlis PRO. Oxford Diffraction Ltd, Yarnton, England.]$ ); cell refinement: CrysAlis PRO; data reduction: CrysAlis PRO; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: DIAMOND (Crystal Impact, 2007 ); software used to prepare material for publication: SHELXL97.

Supporting information

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810008834/rz2423sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536810008834/rz2423Isup2.hkl

checkCIF report

Comment top

The complexes of carboxylic acids with metals, e.g. zinc, are interesting due to different coordination modes of a carboxylate group bound to a metal ion. It is well documented that heterocyclic compounds, especially N-donor ligand systems, play a significant role in many biological systems, being a component of several vitamins and drugs (Nagar, 1990; Cavagiolio et al., 2000). As a part of our ongoing studies of zinc(II) carboxylates (Györyová et al., 2005; Györyová et al., 2006; Bujdošová et al., 2009) we have been exploring the synthesis and crystal structure of zinc(II) 5-bromosalicylate containing N-methylnicotinamide, shown at in vitro study to be a potent anti-inflammatory agent (Gebicki et al., 2003).

In the title monomeric complex [Zn(C₇H₄BrO₃)₂(C₇H₈N₂O)₂(H₂O)₂] (Fig. 1), the zinc(II) atom, which lies on an inversion centre, exhibits a slightly distorted octahedral coordination geometry. The coordination sphere consists of three pairs of trans-arranged monodentate ligands. The two N-methylnicotinamide ligands are coordinated to the zinc atom through nitrogen atoms of the pyridine rings. The 5-bromosalicylate anion is coordinated through one oxygen atom of the carboxylate group. The similar distances O1—C1 (1.256 (2) Å) and O2—C1 (1.262 (2) Å) in the carboxylate group indicate a delocalized bonding arrangement and may be compared with the corresponding distances found in [Zn(C₇H₄ClO₂)₂(C₁₀H₁₄N₂O)₂(H₂O)₂] (Sarı et al., 2007). The plane of the carboxylate group is approximately coplanar with the plane of the benzene ring; the dihedral angle between these planes is 5.5 (3)°. Such behaviour is not unusual; a similar arrangement was observed in other compounds (e.g. diaquabis(N,N-diethylnicotinamide-N)bis(4-fluorobenzoato-O)zinc(II) (Hökelek et al., 2007)). All other geometric parameters of the coordinated anion are similar to that found in free 5-bromosalicylic acid (Liu et al., 2004). The distorted octahedral coordination is completed by two pyridine nitrogen atoms of two N-methylnicotinamide ligands in the axial positions. The Zn—N distance (2.1583 (9) Å) is in good agreement with the values reported for other octahedrally coordinated zinc(II) complexes [viz., Diaquabis(4-chlorobenzoato)bis(N,N-diethylnicotinamide)zinc(II), Zn—N: 2.157 (3) Å; Sarı et al., 2007]. The coordination environment of the zinc(II) atom is completed by water molecules, forming with carboxylate oxygen atoms the basal plane of the distorted octahedron. The Zn—O distance (2.1396 (8) Å) is comparable with those found in similar compounds [viz. diaquabis(2-bromobenzoato)bis(N,N-diethylnicotinamide)zinc(II), Zn—O: 2.1269 (12) Å; Hökelek et al., 2009b]. Intramolecular hydrogen bonding interactions involving the hydroxyl groups and carboxylate oxygen atoms (O3—H1O3···O2) and the equatorially coordinated water molecule and carboxylate oxygen atom (O5—H2O5···O2) stabilize the molecular structure (Fig. 2). Intramolecular hydrogen bonds also influences the orientation and delocalized character of carboxylate group. The molecules of the title compound are linked into a two-dimensional network perpendicular to [100] by intermolecular O5—H1O5···O4 and N2—H1N2···O3 hydrogen bonds (Fig. 3).

Related literature top

For general background to the properties of carboxylic acid–metal complexes, see: Nagar (1990); Cavagiolio et al. (2000). For the synthesis and properties of zinc(II) carboxylates reported by our group, see: Györyová et al. (2005, 2006); Bujdošová et al. (2009); Gebicki et al. (2003). For related structures, see: Necefoglu et al. (2001a,b); Hökelek et al. (2007, 2009a,b); Öztürk et al. (2008); Sarı et al. (2007); Liu et al. (2004).

Experimental top

Analytical reagent grade chemicals were used for the preparation of the title compound. The synthesis was carried out by reaction of aqueous solutions (20 ml) of ZnCl₂ (0.14 g, 1 mmol) and NaHCO₃ (0.17 g, 2 mmol). After complete removal of chloride anions, an acetone solution (10 ml) of 5-bromosalicylic acid (0.44 g, 2 mmol) was added. The resulting solution of (5-BrC₆H₃-2-(OH)COO)₂Zn (0.50 g, 1 mmol) was mixed with an aqueous solution (10 ml) of N-methylnicotinamide (0.27 g, 2 mmol). The reaction mixture was stirred for 2 h and left aside for crystallization at room temperature. After two days, a small amount of colourless bright crystals appeared. The resulting crystals were isolated by filtration.

Computing details top

Data collection: CrysAlis PRO (Oxford Diffraction, 2009); cell refinement: CrysAlis PRO (Oxford Diffraction, 2009); data reduction: CrysAlis PRO (Oxford Diffraction, 2009); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: DIAMOND (Crystal Impact, 2007); software used to prepare material for publication: SHELXL97 (Sheldrick, 2008).

Figures top

	Fig. 1. The molecular structure of the title compound with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Symmetry code: (i) 1-x, -y, -z.
	Fig. 2. View of the intramolecular hydrogen bonds (dashed lines) of the title compound. Hydrogen atoms of aromatic rings and methyl groups are omitted for clarity.
	Fig. 3. View of the intermolecular hydrogen bonds (dashed lines) of the title compound. Hydrogen atoms of aromatic rings and methyl groups are omitted for clarity. Symmetry codes: (i) x, -1+y, z; (ii) x, y, 1+z

Diaquabis(5-bromo-2-hydroxybenzoato)bis(N-methylnicotinamide)zinc(II) top

Crystal data top

[Zn(C₇H₄BrO₃)₂(C₇H₈N₂O)₂(H₂O)₂]	Z = 1
M_r = 805.73	F(000) = 404
Triclinic, P1	D_x = 1.760 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 8.1600 (2) Å	Cell parameters from 19248 reflections
b = 10.1122 (3) Å	θ = 3.0–29.6°
c = 10.4291 (3) Å	µ = 3.50 mm⁻¹
α = 66.800 (3)°	T = 290 K
β = 74.334 (2)°	Prism, colourless
γ = 80.743 (2)°	0.57 × 0.30 × 0.26 mm
V = 760.15 (4) Å³

Data collection top

Oxford Diffraction Xcalibur Sapphire2 diffractometer	3153 independent reflections
Radiation source: Enhance (Mo) X-ray Source	2686 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.024
Detector resolution: 8.3438 pixels mm^-1	θ_max = 26.5°, θ_min = 3.0°
ω scans	h = −10→10
Absorption correction: numerical [Clark & Reid (1995) in CrysAlis PRO (Oxford Diffraction, 2009)]	k = −12→12
T_min = 0.289, T_max = 0.484	l = −13→13
32240 measured reflections

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.022	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.064	H-atom parameters constrained
S = 1.15	w = 1/[σ²(F_o²) + (0.0404P)²] where P = (F_o² + 2F_c²)/3
3153 reflections	(Δ/σ)_max < 0.001
195 parameters	Δρ_max = 0.50 e Å⁻³
0 restraints	Δρ_min = −0.49 e Å⁻³

Crystal data top

[Zn(C₇H₄BrO₃)₂(C₇H₈N₂O)₂(H₂O)₂]	γ = 80.743 (2)°
M_r = 805.73	V = 760.15 (4) Å³
Triclinic, P1	Z = 1
a = 8.1600 (2) Å	Mo Kα radiation
b = 10.1122 (3) Å	µ = 3.50 mm⁻¹
c = 10.4291 (3) Å	T = 290 K
α = 66.800 (3)°	0.57 × 0.30 × 0.26 mm
β = 74.334 (2)°

Data collection top

Oxford Diffraction Xcalibur Sapphire2 diffractometer	3153 independent reflections
Absorption correction: numerical [Clark & Reid (1995) in CrysAlis PRO (Oxford Diffraction, 2009)]	2686 reflections with I > 2σ(I)
T_min = 0.289, T_max = 0.484	R_int = 0.024
32240 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.022	0 restraints
wR(F²) = 0.064	H-atom parameters constrained
S = 1.15	Δρ_max = 0.50 e Å⁻³
3153 reflections	Δρ_min = −0.49 e Å⁻³
195 parameters

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Zn1	0.5000	0.0000	0.0000	0.02312 (9)
O1	0.67676 (14)	−0.02707 (13)	−0.17587 (12)	0.0305 (3)
O2	0.5864 (2)	0.14251 (15)	−0.36177 (15)	0.0493 (4)
O3	0.6562 (2)	0.11216 (16)	−0.60156 (15)	0.0550 (4)
H1O3	0.6075	0.1466	−0.5409	0.083*
C1	0.6699 (2)	0.02704 (19)	−0.30545 (19)	0.0299 (4)
C2	0.7659 (2)	−0.05359 (18)	−0.40050 (18)	0.0270 (4)
C3	0.7497 (2)	−0.00760 (19)	−0.54230 (19)	0.0348 (4)
C4	0.8343 (3)	−0.0873 (2)	−0.6265 (2)	0.0425 (5)
H4	0.8233	−0.0574	−0.7204	0.051*
C5	0.9340 (3)	−0.2099 (2)	−0.5713 (2)	0.0403 (5)
H5	0.9899	−0.2629	−0.6276	0.048*
C6	0.9505 (2)	−0.25379 (19)	−0.43114 (19)	0.0319 (4)
C7	0.8667 (2)	−0.17721 (18)	−0.34631 (18)	0.0295 (4)
H7	0.8777	−0.2085	−0.2522	0.035*
Br1	1.08861 (3)	−0.42202 (2)	−0.35493 (2)	0.05222 (9)
N1	0.66055 (11)	0.14385 (9)	0.01039 (9)	0.0245 (3)
N2	0.48397 (11)	0.41145 (9)	0.24800 (9)	0.0384 (4)
H1N2	0.4560	0.3237	0.2876	0.046*
C8	0.82847 (11)	0.13682 (9)	−0.04349 (9)	0.0302 (4)
H8	0.8741	0.0682	−0.0843	0.036*
C9	0.9368 (2)	0.2262 (2)	−0.0414 (2)	0.0373 (4)
H9	1.0533	0.2178	−0.0794	0.045*
C10	0.8694 (2)	0.32926 (19)	0.0186 (2)	0.0352 (4)
H10	0.9399	0.3919	0.0205	0.042*
C11	0.6960 (2)	0.33753 (16)	0.07550 (17)	0.0250 (3)
C12	0.5966 (2)	0.24263 (16)	0.06900 (17)	0.0241 (3)
H12	0.4799	0.2479	0.1072	0.029*
C13	0.6211 (2)	0.44766 (17)	0.14122 (19)	0.0282 (4)
C14	0.39754 (10)	0.50534 (8)	0.32554 (9)	0.0531 (6)
H14C	0.2890	0.4692	0.3828	0.080*
H14A	0.3809	0.6011	0.2583	0.080*
H14B	0.4660	0.5074	0.3864	0.080*
O4	0.68500 (13)	0.56491 (9)	0.09551 (11)	0.0373 (3)
O5	0.63493 (12)	−0.17592 (8)	0.13428 (10)	0.0300 (3)
H2O5	0.5760	−0.1834	0.2138	0.045*
H1O5	0.6509	−0.2531	0.1229	0.045*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Zn1	0.02369 (15)	0.02253 (14)	0.02842 (16)	−0.00151 (10)	−0.00284 (11)	−0.01690 (11)
O1	0.0301 (6)	0.0377 (7)	0.0285 (7)	−0.0004 (5)	−0.0009 (5)	−0.0214 (6)
O2	0.0659 (10)	0.0349 (7)	0.0386 (8)	0.0174 (7)	−0.0051 (7)	−0.0168 (6)
O3	0.0737 (11)	0.0479 (9)	0.0376 (9)	0.0209 (8)	−0.0187 (8)	−0.0152 (7)
C1	0.0294 (9)	0.0296 (9)	0.0322 (10)	−0.0047 (7)	0.0013 (7)	−0.0175 (8)
C2	0.0290 (9)	0.0285 (9)	0.0242 (9)	−0.0033 (7)	0.0008 (7)	−0.0143 (7)
C3	0.0416 (11)	0.0330 (10)	0.0272 (9)	−0.0004 (8)	−0.0060 (8)	−0.0102 (8)
C4	0.0580 (13)	0.0465 (12)	0.0239 (10)	0.0003 (10)	−0.0069 (9)	−0.0170 (9)
C5	0.0489 (12)	0.0433 (11)	0.0322 (10)	−0.0008 (9)	0.0002 (9)	−0.0246 (9)
C6	0.0315 (10)	0.0310 (9)	0.0344 (10)	0.0009 (7)	−0.0031 (8)	−0.0172 (8)
C7	0.0321 (9)	0.0342 (9)	0.0247 (9)	−0.0028 (7)	−0.0033 (7)	−0.0152 (7)
Br1	0.05614 (16)	0.04580 (14)	0.05557 (16)	0.01938 (10)	−0.01506 (11)	−0.02663 (11)
N1	0.0260 (7)	0.0214 (7)	0.0303 (8)	−0.0008 (5)	−0.0066 (6)	−0.0140 (6)
N2	0.0486 (10)	0.0283 (8)	0.0416 (10)	−0.0049 (7)	−0.0014 (8)	−0.0213 (7)
C8	0.0287 (9)	0.0277 (9)	0.0376 (10)	0.0011 (7)	−0.0036 (7)	−0.0192 (8)
C9	0.0248 (9)	0.0371 (10)	0.0539 (12)	−0.0040 (8)	−0.0013 (8)	−0.0249 (9)
C10	0.0346 (10)	0.0300 (9)	0.0462 (11)	−0.0087 (7)	−0.0085 (8)	−0.0173 (8)
C11	0.0327 (9)	0.0181 (8)	0.0272 (9)	−0.0012 (6)	−0.0100 (7)	−0.0097 (7)
C12	0.0262 (8)	0.0215 (8)	0.0273 (9)	0.0006 (6)	−0.0069 (7)	−0.0122 (7)
C13	0.0331 (9)	0.0229 (8)	0.0359 (10)	0.0034 (7)	−0.0163 (7)	−0.0151 (7)
C14	0.0612 (15)	0.0488 (13)	0.0547 (14)	−0.0050 (11)	0.0057 (11)	−0.0365 (11)
O4	0.0450 (8)	0.0217 (6)	0.0504 (8)	−0.0032 (5)	−0.0097 (6)	−0.0191 (6)
O5	0.0316 (7)	0.0239 (6)	0.0381 (7)	0.0014 (5)	−0.0059 (5)	−0.0175 (5)

Geometric parameters (Å, º) top

Zn1—O1ⁱ	2.0879 (11)	N1—C8	1.3352 (13)
Zn1—O1	2.0879 (11)	N1—C12	1.3359 (17)
Zn1—O5	2.1396 (9)	N2—C13	1.328 (2)
Zn1—O5ⁱ	2.1396 (9)	N2—C14	1.4609 (13)
Zn1—N1ⁱ	2.1583 (9)	N2—H1N2	0.8578
Zn1—N1	2.1583 (9)	C8—C9	1.372 (2)
O1—C1	1.256 (2)	C8—H8	0.9300
O2—C1	1.262 (2)	C9—C10	1.387 (2)
O3—C3	1.341 (2)	C9—H9	0.9300
O3—H1O3	0.8200	C10—C11	1.382 (2)
C1—C2	1.508 (2)	C10—H10	0.9300
C2—C7	1.386 (2)	C11—C12	1.384 (2)
C2—C3	1.402 (3)	C11—C13	1.497 (2)
C3—C4	1.396 (2)	C12—H12	0.9300
C4—C5	1.377 (3)	C13—O4	1.235 (2)
C4—H4	0.9300	C14—H14C	0.9600
C5—C6	1.389 (3)	C14—H14A	0.9600
C5—H5	0.9300	C14—H14B	0.9600
C6—C7	1.376 (2)	O5—H2O5	0.8196
C6—Br1	1.8968 (18)	O5—H1O5	0.8197
C7—H7	0.9300

O1ⁱ—Zn1—O1	180.00 (8)	C6—C7—H7	119.9
O1ⁱ—Zn1—O5	92.30 (4)	C2—C7—H7	119.9
O1—Zn1—O5	87.70 (4)	C8—N1—C12	117.96 (11)
O1ⁱ—Zn1—O5ⁱ	87.70 (4)	C8—N1—Zn1	120.28 (7)
O1—Zn1—O5ⁱ	92.30 (4)	C12—N1—Zn1	121.77 (9)
O5—Zn1—O5ⁱ	180.00 (10)	C13—N2—C14	122.98 (11)
O1ⁱ—Zn1—N1ⁱ	91.23 (4)	C13—N2—H1N2	120.1
O1—Zn1—N1ⁱ	88.77 (4)	C14—N2—H1N2	115.5
O5—Zn1—N1ⁱ	91.78 (3)	N1—C8—C9	122.98 (11)
O5ⁱ—Zn1—N1ⁱ	88.22 (3)	N1—C8—H8	118.5
O1ⁱ—Zn1—N1	88.77 (4)	C9—C8—H8	118.5
O1—Zn1—N1	91.23 (4)	C8—C9—C10	118.76 (15)
O5—Zn1—N1	88.22 (4)	C8—C9—H9	120.6
O5ⁱ—Zn1—N1	91.78 (3)	C10—C9—H9	120.6
N1ⁱ—Zn1—N1	180.00 (4)	C11—C10—C9	118.99 (16)
C1—O1—Zn1	128.42 (11)	C11—C10—H10	120.5
C3—O3—H1O3	109.5	C9—C10—H10	120.5
O1—C1—O2	125.03 (16)	C10—C11—C12	118.22 (15)
O1—C1—C2	117.54 (15)	C10—C11—C13	119.77 (15)
O2—C1—C2	117.42 (16)	C12—C11—C13	122.01 (15)
C7—C2—C3	119.42 (15)	N1—C12—C11	123.07 (14)
C7—C2—C1	119.96 (15)	N1—C12—H12	118.5
C3—C2—C1	120.57 (16)	C11—C12—H12	118.5
O3—C3—C4	118.17 (17)	O4—C13—N2	123.41 (16)
O3—C3—C2	122.26 (16)	O4—C13—C11	120.51 (15)
C4—C3—C2	119.57 (17)	N2—C13—C11	116.08 (15)
C5—C4—C3	120.41 (18)	N2—C14—H14C	109.5
C5—C4—H4	119.8	N2—C14—H14A	109.5
C3—C4—H4	119.8	H14C—C14—H14A	109.5
C4—C5—C6	119.57 (17)	N2—C14—H14B	109.5
C4—C5—H5	120.2	H14C—C14—H14B	109.5
C6—C5—H5	120.2	H14A—C14—H14B	109.5
C7—C6—C5	120.74 (17)	Zn1—O5—H2O5	100.9
C7—C6—Br1	119.51 (14)	Zn1—O5—H1O5	119.2
C5—C6—Br1	119.74 (14)	H2O5—O5—H1O5	111.8
C6—C7—C2	120.28 (16)

O5—Zn1—O1—C1	167.76 (16)	O1—Zn1—N1—C8	−24.26 (8)
O5ⁱ—Zn1—O1—C1	−12.24 (16)	O5—Zn1—N1—C8	63.39 (8)
N1ⁱ—Zn1—O1—C1	75.93 (14)	O5ⁱ—Zn1—N1—C8	−116.61 (8)
N1—Zn1—O1—C1	−104.07 (14)	O1ⁱ—Zn1—N1—C12	−24.81 (11)
Zn1—O1—C1—O2	24.7 (3)	O1—Zn1—N1—C12	155.19 (11)
Zn1—O1—C1—C2	−153.98 (11)	O5—Zn1—N1—C12	−117.16 (10)
O1—C1—C2—C7	−4.4 (2)	O5ⁱ—Zn1—N1—C12	62.84 (10)
O2—C1—C2—C7	176.77 (16)	C12—N1—C8—C9	−0.15 (17)
O1—C1—C2—C3	173.34 (16)	Zn1—N1—C8—C9	179.32 (11)
O2—C1—C2—C3	−5.5 (3)	N1—C8—C9—C10	−0.4 (2)
C7—C2—C3—O3	−178.98 (17)	C8—C9—C10—C11	0.7 (3)
C1—C2—C3—O3	3.3 (3)	C9—C10—C11—C12	−0.5 (3)
C7—C2—C3—C4	0.4 (3)	C9—C10—C11—C13	179.74 (17)
C1—C2—C3—C4	−177.40 (16)	C8—N1—C12—C11	0.3 (2)
O3—C3—C4—C5	179.01 (19)	Zn1—N1—C12—C11	−179.13 (12)
C2—C3—C4—C5	−0.4 (3)	C10—C11—C12—N1	0.0 (2)
C3—C4—C5—C6	−0.2 (3)	C13—C11—C12—N1	179.73 (14)
C4—C5—C6—C7	0.8 (3)	C14—N2—C13—O4	−2.0 (2)
C4—C5—C6—Br1	−179.66 (15)	C14—N2—C13—C11	178.73 (11)
C5—C6—C7—C2	−0.8 (3)	C10—C11—C13—O4	31.6 (2)
Br1—C6—C7—C2	179.66 (13)	C12—C11—C13—O4	−148.18 (17)
C3—C2—C7—C6	0.2 (3)	C10—C11—C13—N2	−149.10 (16)
C1—C2—C7—C6	178.00 (16)	C12—C11—C13—N2	31.1 (2)
O1ⁱ—Zn1—N1—C8	155.74 (8)

Symmetry code: (i) −x+1, −y, −z.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O3—H1O3···O2	0.82	1.81	2.540 (2)	147
N2—H1N2···O3ⁱⁱ	0.86	2.55	3.1109 (19)	123
O5—H2O5···O2ⁱ	0.82	1.88	2.6694 (18)	162
O5—H1O5···O4ⁱⁱⁱ	0.82	1.94	2.7568 (13)	179

Symmetry codes: (i) −x+1, −y, −z; (ii) x, y, z+1; (iii) x, y−1, z.

Experimental details

Crystal data
Chemical formula	[Zn(C₇H₄BrO₃)₂(C₇H₈N₂O)₂(H₂O)₂]
M_r	805.73
Crystal system, space group	Triclinic, P1
Temperature (K)	290
a, b, c (Å)	8.1600 (2), 10.1122 (3), 10.4291 (3)
α, β, γ (°)	66.800 (3), 74.334 (2), 80.743 (2)
V (Å³)	760.15 (4)
Z	1
Radiation type	Mo Kα
µ (mm⁻¹)	3.50
Crystal size (mm)	0.57 × 0.30 × 0.26

Data collection
Diffractometer	Oxford Diffraction Xcalibur Sapphire2 diffractometer
Absorption correction	Numerical [Clark & Reid (1995) in CrysAlis PRO (Oxford Diffraction, 2009)]
T_min, T_max	0.289, 0.484
No. of measured, independent and observed [I > 2σ(I)] reflections	32240, 3153, 2686
R_int	0.024
(sin θ/λ)_max (Å⁻¹)	0.628

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.022, 0.064, 1.15
No. of reflections	3153
No. of parameters	195
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.50, −0.49

Computer programs: CrysAlis PRO (Oxford Diffraction, 2009), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), DIAMOND (Crystal Impact, 2007).

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O3—H1O3···O2	0.82	1.81	2.540 (2)	146.8
N2—H1N2···O3ⁱ	0.86	2.55	3.1109 (19)	123.4
O5—H2O5···O2ⁱⁱ	0.82	1.88	2.6694 (18)	161.7
O5—H1O5···O4ⁱⁱⁱ	0.82	1.94	2.7568 (13)	179.1

Symmetry codes: (i) x, y, z+1; (ii) −x+1, −y, −z; (iii) x, y−1, z.

Acknowledgements

Financial support by the Slovak Ministry of Education (VEGA project No. 1/0122/08) is gratefully acknowledged.

References

Bujdošová, Z., Györyová, K., Kovářová, J., Hudecová, D. & Halás, L. (2009). J. Therm. Anal. Calorim. 98, 151–159. Google Scholar
Cavagiolio, G., Benedetto, L., Boccaleri, E., Colangelo, D., Viano, I. & Osella, D. (2000). Inorg. Chim. Acta, 305, 61–68. Google Scholar
Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887–897. CrossRef CAS Web of Science IUCr Journals Google Scholar
Crystal Impact (2007). DIAMOND. Crystal Impact, Bonn, Germany. Google Scholar
Gebicki, J., Sysa-Jedrzejowska, A. & Adamus, J. (2003). Pol. J. Pharmacol. 55, 109–112. Web of Science PubMed CAS Google Scholar
Györyová, K., Chomič, J. & Kovářová, J. (2005). J. Therm. Anal. Calorim. 80, 375–380. Google Scholar
Györyová, K., Chomič, J., Szunyogová, E., Piknová, L., Zeleňák, V. & Vargová, Z. (2006). J. Therm. Anal. Calorim. 84, 727–732. Google Scholar
Hökelek, T., Çaylak, N. & Necefoğlu, H. (2007). Acta Cryst. E63, m2561–m2562. Web of Science CSD CrossRef IUCr Journals Google Scholar
Hökelek, T., Dal, H., Tercan, B., Özbek, F. E. & Necefoğlu, H. (2009a). Acta Cryst. E65, m607–m608. Web of Science CSD CrossRef IUCr Journals Google Scholar
Hökelek, T., Dal, H., Tercan, B., Özbek, F. E. & Necefoğlu, H. (2009b). Acta Cryst. E65, m481–m482. Web of Science CSD CrossRef IUCr Journals Google Scholar
Liu, Z.-D., Qu, Y., Tan, M.-Y. & Zhu, H.-L. (2004). Acta Cryst. E60, o1310–o1311. Web of Science CSD CrossRef IUCr Journals Google Scholar
Nagar, R. (1990). J. Inorg. Biochem. 40, 349–356. CrossRef CAS PubMed Web of Science Google Scholar
Necefoglu, H., Clegg, W. & Scott, A. J. (2001a). Acta Cryst. E57, m462–m464. Web of Science CSD CrossRef IUCr Journals Google Scholar
Necefoglu, H., Clegg, W. & Scott, A. J. (2001b). Acta Cryst. E57, m465–m466. Web of Science CSD CrossRef IUCr Journals Google Scholar
Oxford Diffraction (2009). CrysAlis PRO. Oxford Diffraction Ltd, Yarnton, England. Google Scholar
Öztürk, A., Hökelek, T., Özbek, F. E. & Necefoğlu, H. (2008). Acta Cryst. E64, m1218–m1219. Web of Science CSD CrossRef IUCr Journals Google Scholar
Sarı, M., Gökçe, G., Gökçe, S., Şahin, E. & Necefoğlu, H. (2007). Acta Cryst. E63, m2191. Web of Science CSD CrossRef IUCr Journals Google Scholar
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. Web of Science CrossRef CAS IUCr Journals Google Scholar