issue contents
July 1995 issue
inorganic compounds
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The tetrahedrally close-packed structure of Co6.3Nb6.7 is built up from five crystallographically distinct atoms having coordination numbers 12, 14, 15 and 16. The relative frequencies of the coordination numbers are 7:2:2:2.
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The structure of Sr5Nb5O17 contains distorted perovskite-type slabs parallel to (100) formed from five NbO6 octahedra and Sr atoms. The compound is isotypic with La5Ti5O17 and both structures belong to the homologous series An+1Bn+1O3n+5 with n = 4.
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In the mixed anionic framework structure of K3[Al4F9(PO4)2] a new type of branched octahedral chain, formed by cis-AlF4O2 octahedra sharing common vertices, is interconnected by PO43− anions.
metal-organic compounds
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organic compounds
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