issue contents

Journal logoSTRUCTURAL
CHEMISTRY
ISSN: 2053-2296

March 1998 issue

Highlighted illustration

Cover illustration: A Novel Cyclotriphosphazene Complex with a Short Transannular P...P Contact, see Thomas, pages 331-333. Displacement ellipsoids are shown at the 50% probability level for non-H atoms and H atoms have been omitted for clarity.

cif-access (organic compounds)


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In the title compound (efaroxan hydrochloride), homochiral cationic molecules form chains along the b axis of the triclinic cell via N-H⋯Cl hydrogen bonds. The furanyl groups are nearly parallel to the a axis and the imidazolinium rings are roughly perpendicular to it.

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The structure and relative stereochemistry of O-methyldehydronorcacalol, a sesquiterpenoid isolated from Traversia baccharoides Hook f., is established. The hydroxyl group takes part in a bifurcated hydrogen bond, intramolecular with an adjacent methoxy O atom and intermolecular with an acetyl O atom of an adjacent molecule.

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1,3-Oxazolidines are powerful chiral templates for auxiliary-directed asymmetric synthesis. The stereochemical parameters of the title compound are in good agreement with other arylsulfonyloxazolidines.

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In the title molecule, the dihydropyran ring adopts a sofa conformation. The benzopyran ring is distorted from planarity and the phenyl ring forms a dihedral angle of 53.86 (6)° with the dihydropyran ring.

inorganic compounds


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A new synthetic route for the preparation of single crystals of monoclinic VOHPO4.2H2O has been found. The results of the single-crystal structure analysis are compared with those of an earlier X-ray powder structure determination.

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Special and virtual issues

Acta Crystallographica Section C is planning special issues on

The Structural Chemistry of Homogeneous and Heterogeneous Catalysts

NMR Crystallography.

Full details are available on the special issues page.

The latest virtual issue, featuring Coordination polymers and with an introduction by Len Barbour, was published in July 2014.

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