issue contents
July 2000 issue
inorganic compounds
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The single-crystal structure of the title compound shows the anion to have the Anderson structure based on six WO6 octahedral edge-sharing units surrounding a central MnO6 octahedron. Varying interactions from the O atoms of the MnO6 octahedron to surrounding water molecules result in differences in the Mn—O distances.
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Precise X-ray structural determinations of two Cr3+ α-alums are presented, each at 293 and at 12 K.
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Precise X-ray structural determinations of Cs2K[Mn(CN)6] at 293, 85 and 10 K have been performed. The centrosymmetric [Mn(CN)6]3− anion has very close to regular octahedral stereochemistry.
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The structure of dipotassium titanium trisilicate hydrate has been refined and the hydrogen-bonding geometry elucidated. The structure is a three-dimensional mixed framework with channels formed by six- and eight-membered rings. K+ ions and water molecules are located in the channels.
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The title structure contains typical centrosymmetric OV6 double octahedra and centrosymmetric pairs of edge-shared NaO6 double octahedra forming a layered structure.
metal-organic compounds
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This new organic zincoarsenate is built up from a two-dimensional framework of ZnO5 and ZnO6 polyhedra, and AsO4 tetrahedra. Trigonally coordinated O atoms are present in these layers. The organic cations are inserted between the inorganic sheets.
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organic compounds
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