issue contents

Journal logoSTRUCTURAL
CHEMISTRY
ISSN: 2053-2296

February 2001 issue

Highlighted illustration

Cover illustration: The packing diagram for tetra­thio­ureamercury(II) tetra­thio­cyan­ato­mangan­ate(II) viewed down the c axis. See Yu, Wang, Xu, Lu & Yuan [Acta Cryst. (2001), C57, 145-146].

inorganic compounds


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The title compound is a double-layered hydro­xide which belongs to the solid solution Ca2Al(OH)6BrxCl1−x·2H2O, where x can vary from 0 to 1. Chloride and bromide anions of the negatively charged interlayer [Br0.5Cl0.5·2H2O] share statistically the same crystallographic site. Al3+ and Ca2+ cations are coordinated by six and seven O atoms, respectively. All water mol­ecules are bonded to Ca2+ cations and assume the seventh coordination position.

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Cs3CoCl5 has been determined at 10 K with high precision. The Co atom is at a site with {\bar 4}2m symmetry, one Cs atom is at a site with 42 symmetry, the other has mm site symmetry, one Cl ligand has 4/m symmetry and the other has m symmetry.

metal-organic compounds












organic compounds
























Special and virtual issues

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Acta Crystallographica Section C is planning special issues on

The Structural Chemistry of Homogeneous and Heterogeneous Catalysts

NMR Crystallography.

Full details are available on the special issues page.

The latest virtual issue, featuring Coordination polymers and with an introduction by Len Barbour, was published in July 2014.

What are the 'most read' articles from the recent special issues?

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