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February 2001 issue
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Cover illustration: The packing diagram for tetrathioureamercury(II) tetrathiocyanatomanganate(II) viewed down the c axis. See Yu, Wang, Xu, Lu & Yuan [Acta Cryst. (2001), C57, 145-146].
inorganic compounds
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The title compound is a double-layered hydroxide which belongs to the solid solution Ca2Al(OH)6BrxCl1−x·2H2O, where x can vary from 0 to 1. Chloride and bromide anions of the negatively charged interlayer [Br0.5Cl0.5·2H2O]− share statistically the same crystallographic site. Al3+ and Ca2+ cations are coordinated by six and seven O atoms, respectively. All water molecules are bonded to Ca2+ cations and assume the seventh coordination position.
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Cs3CoCl5 has been determined at 10 K with high precision. The Co atom is at a site with
symmetry, one Cs atom is at a site with 42 symmetry, the other has mm site symmetry, one Cl ligand has 4/m symmetry and the other has m symmetry.
![{\bar 4}2m](/c/issues/2001/02/00/br1294/teximages/br1294fi1.gif)
metal-organic compounds
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organic compounds
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