A non-linear optical crystal, Cd₃Zn₃(BO₃)₄

A single crystal, 3 × 1.5 × 1 mm, of Cd₃Zn₃(BO₃)₄ has been prepared by spontaneous nucleation and its strong second harmonic generation of Nd:YAG laser radiation (λ 1064 nm) has been observed.

[Yb(H₂O)₈][Cd₃Cl₉(H₂O)]·6H₂O

A new hydrated double salt, YbCd₃Cl₉·15H₂O, has been synthesized, and its structure has been determined by single-crystal X-ray diffraction and compared with that of CeCd₄Cl₁₁·13H₂O. The structure of the ytterbium compound contains a layered arrangement of Cd octahedra, with a decrease of the coordination number of the rare-earth cation from nine for Ce³⁺ to eight for Yb³⁺.

Cs₆Mo₂₇S₃₁: a novel ternary reduced molybdenum sulfide containing Mo₉ and Mo₁₈ clusters

Cs₆Mo₂₇S₃₁ is the third member of the Cs_2nMo₉S₁₁Mo_6nS_6n+2 series. The crystal structure consists of an equal mixture of Mo₉S₁₁S₆ and Mo₁₈S₂₀S₆ cluster units that are separated by Cs⁺ cations.

A new hydrated ammonium hy­droxy­borate, (NH₄)₂[B₁₀O₁₄(OH)₄]·H₂O

In the title compound, the fundamental building blocks are connected to form infinite chains. These chains are linked via hydrogen bonds, thus forming sheets that are stacked along the [001] direction.

Di­aqua­bis­(1,10-phenanthroline-κ²N,N′)­manganese(II) thiodiglycolate bis­(1,10-phenanthroline-κ²N,N′)(thiodiglycolato-κ²O,O′)­manganese(II) tridecahydrate

Hexa­fluoro­phosphates of chloro­tris­(di­methyl sulfide)­platinum(II) and bromo­tris­(di­methyl sulfide)­platinum(II)

Magnesium iodide–4,4′-bi­pyridine–water (1/3/4) and strontium iodide–4,4′-bi­pyridine–propan-1-ol (1/2.5/2)

A tri­chloro-bridged binuclear ruthenium complex with 1,1,1-tris­(di­phenylphosphino­methyl)ethane

Di­chloro­bis­(imidazolidin-2-one-κO)­zinc(II) at 150 K

[(1R,2R)-1,2-Di­amino­cyclo­hexane-κ²N,N′](α-di­imine-κ²N,N′)­platinum(II) bis­(hexa­fluoro­phosphate), where α-di­imine is 2,2′-bi­pyridine and 1,10-phen­anthroline

A barium perchlorate complex with a lateral macrobicycle derived from 4,13-di­aza-18-crown-6 containing a pyridine Schiff base spacer

A dimeric heteroleptic five-coordinate zinc(II) complex containing a non-motionally restricted N,N′-heterocyclic ligand

catena-Poly[[(1,10-phenanthroline-κ²N,N′)copper(II)]-μ-(di­hydrogen benzene-1,2,4,5-tetra­carboxylato)-κ²O¹:O⁴]

Polymeric di­hydroxydiphthalatotricobalt(II)

Hemi(piperazinediium) hexa­aqua­aluminium(III) bis­(sulfate) tetrahydrate: a new double aluminium sulfate salt

Bis(2-chloro-5-methylpyridine-κN)bis­(nitrato-κ²O,O′)copper(II)

Bis­(tetra­phenyl­phospho­nium) (μ-tetra­thio­tungstenio-κ⁴S,S′:S′′:S′′′)­bis­[(cyano-κC)­cuprate](2–) aceto­nitrile solvate monohydrate

Geometric isomers of chloro(6-methyl-1,4,8,11-tetra­aza­cyclotetra­decane-6-amine)cobalt(III) tetra­chlorozincate(II)

(C₄N₂H₁₂)[(GeO₂)₃(BO_1.5F)₂], a layered borogermanate containing three- and nine-membered rings

A new borogermanate, (C₄H₁₂N₂)[(GeO₂)₃(BO_1.5F)₂], was solvo/hydro­thermally synthesized. It has a layered structure containing three- and nine-membered rings built from GeO₄ and BO₃F tetrahedra. The layers are connected through hydrogen bonding via diprotonated piperazine cations located between the layers.

Chlorobis[N′-ethoxycarbonyl-N-(4-methylphenyl)thiourea-κS]copper(I)

Poly[sodium(I)-μ₆-hydrogen benzene-1,4-di­carboxylato]

Influence of Cl/Br substitution on the stereochemical peculiarities of copper(I) π-complexes with the 1-allyl-2-amino­pyridinium cation

A novel Cd^II coordination polymer with 1,1′-(1,4-butanediyl)di­imidazole

Tetra­phenylarsonium iodide, a new determination

{Bis­[(S)-2-(4-tert-butyl-4,5-di­hydro­oxazol-2-yl)phenyl]­phenyl­phoshine-κ²N,P}(1,3-di­methyl-π-allyl-κ³C)­palladium(II) hexa­fluoro­phosphate and (S)_P-{bis­[(S)-2-(4-tert-butyl-4,5-di­hydro­oxazol-2-yl)phenyl]phenylphos­phine-κ²N,P}di­chloro­palladium(II)

A one-dimensional copper coordination polymer containing both dicyan­amide and 1,10-phenanthroline ligands

A zirconium zwitterion containing a caged amine H atom

Bis(μ-di-2-pyridyl­aminato 1-oxide)­bis­[(tri­fluoro­acetato)copper(II)] aceto­nitrile disolvate

3,5-Bis­[4-(di­ethyl­amino)­benzyl­idene]-1-methyl-4-piperidone and 3,5-bis­[4-(di­ethyl­amino)­cinnamyl­idene]-1-methyl-4-piperidone: prospective biophotonic materials

7-Meth­oxy­anthra­[1,9-de]-1,3,2-dioxathiine-8,11-dione 2,2-dioxide

2,3-Bis(2-methyl­phenyl­imino)-1,4-di­thia­cyclo­hexane

4,4′-(Azino­dimethyl­ene)­dipyridinium chloranilate di­chloro­methane disolvate

2-{[Tris(hydroxymethyl)methyl]amino­methylene}cyclohexa-3,5-dien-1(2H)-one and its 6-hy­droxy and 6-meth­oxy derivatives

Herring-bone π–π interactions in trans-2,6-di­phenyl-2,3,5,6-tetrahydro­thia­pyran-4-one

4-(Piperidin-1-yl)pyridinium hexa­fluorophosphate at 150 K

N,N-Di­methyl-N′-[(1E,2E)-3-(4-nitro­phenyl)­prop-2-enyl­idene]­benzene-1,4-di­amine and N,N-di­methyl-4-[(1E,3E)-4-(4-nitro­phenyl)­buta-1,3-dienyl]-1-naphthyl­amine

Four cytotoxic N4-substituted thiosemicarbazones derived from 2-hydroxynaphthalene-1-carboxaldehyde

Two polymorphic forms of 2,5-bis­(4-meth­oxy­carbonyl­phenyl)-1,3,4-oxa­diazo­le

Bilayers in 4-iodo-N-(2-iodo-4-nitro­phenyl)benzamide generated by a combination of an N—H⋯O=C hydrogen bond and two independent iodo–nitro interactions

(±)-2-Oxo­cyclo­hexanepropionic acid: dual conformational selection and hydrogen bonding in a δ-keto acid, and a two-phase technique for crystallizing acids by contact with aqueous solutions of their salts

1-(4-Chloro­phenyl­sulfanyl)-2-nitro-4-(tri­fluoro­methyl)­benzene and 1-(4-chloro­phenyl­sulfanyl)-4-nitro-2-(tri­fluoro­methyl)­benzene

A new norkaurane-γ-lactone from Parinari sprucei

(Z)-2-(3-Hy­droxy-4-methoxybenzyl­idene)-1-azabi­cyclo[2.2.2]octan-3-one

Cephalexin: a channel hydrate

4,5-Propyl­enedi­thio-1,3-di­thiole-2-thione and 4,5-propyl­enedi­thio-1,3-di­thiol-2-one

Pseudosymmetry in ammonium [(carboxymethyl)sulfanyl]acetate