issue contents
February 2007 issue
inorganic compounds
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Tb2Ni2Mg3 is a new structure type, derived from Ru3Al2B2, which can be viewed as the first representative of a homologous linear structure series based on the α-Fe, CsCl and AlB2 structure types. The Tb atoms in the structure are enclosed in 17-vertex polyhedra, while rhombododecahedra and distorted rhombododecahedra surround the Mg atoms, and equatorially tricapped trigonal prisms form around the Ni atoms.
metal-organic compounds
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In the structure of [VO(H2O)5](CF3SO3)2, the cation and both anions are situated on crystallographic mirror planes. The cation and anions engage in a number of relatively long hydrogen bonds.
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organic compounds
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