issue contents
August 2007 issue
inorganic compounds
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The title compound contains chains of edge-sharing distorted VO6 octahedra. Pyramidal TeO3 groups and unusual capped trigonal–bipyramidal LiO6 polyhedra complete a three-dimensional structure.
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The structure of the title compound consists of layers of [Ru2Cl10O]4− and [Ba(H2O)7]2+ ions alternating along the c axis. The overall structure is held together by O—H⋯O hydrogen bonds and O—H⋯Cl dipole–dipole interactions.
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KSrNb2O6F consists of double perovskite slabs, [SrNb2O6F]−, and interlayer K+ ions. Within the perovskite slabs, the NbO5F octahedra are tilted about the a axis and the O2− and F− ions exhibit an ordered distribution.
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A new phase with the composition ZnTe6O13 was identified with trigonal (R) symmetry. The structure consists of an infinite three-dimensional network of Zn atoms coordinated in a distorted octahedral fashion by TeO4 and TeO3+1 polyhedra.
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The structural topology of the new synthetic material Ca3GeO4Cl2 is described and compared with the olivine-type Ca2GeO4 and norbergite-type Mg3SiO4F2.
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Tyrrellite, Cu(Co,Ni)2Se4, is a normal spinel containing Cu in a tetrahedral coordination.
metal-organic compounds
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organic compounds
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