issue contents
November 2007 issue
inorganic compounds
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In the structures of Ca[IrF6]·2H2O and Sr[IrF6]·2H2O, the cations have distorted square-antiprismatic coordinations. In Ba[IrF6], the cation has a cuboctahedral coordination. All three structures can be described as frameworks.
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The title compound is isomorphous with the La and Pr members of the Ln3MoO7 series. However, a splitting of one of the lanthanide sites into two positions is observed in Sm3MoO7.
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The structure of the complex phosphate KIn0.5Nb0.5OPO4 is merohedrally twinned about the [110] twofold axis. A cis–cis linkage of [MO6] octahedra embodies a new subclass of 4/m symmetry structures.
metal-organic compounds
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This new hydrate of barium acetate presents six independent barium centres, 12 independent acetate ligands and three complete and one disordered aqua molecule to generate a tight three-dimensional structure in which extensive hydrogen bonding is present.
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organic compounds
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