issue contents
December 2009 issue
inorganic compounds
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The monoclinic compound Cr1.45Tl1.87Mo15Se19 represents a variant of the hexagonal In3Mo15Se19 structure type containing an equal mixture of Mo6Se8Se6 and Mo9Se11Se6 cluster units. The main difference concerns the occupation of a supplementary Cr site at the mid-point of the a axis in the new quaternary compound.
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The title compounds are the first heptavalent actinide compounds containing [AnO4(OH)2]3− anions together with outer-sphere OH groups.
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In KNi5[P6B6O23(OH)13], 12-membered borophosphate rings with K+ ions at the centers are linked by linear trimers of face-sharing [NiO6] octahedra and single [NiO6] octahedra to form a mixed anionic framework.
metal-organic compounds
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organic compounds
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