Gadolinium ytterbium trifluoride, Gd_0.81Yb_0.19F₃

A new gadolinium ytterbium trifluoride has been grown for the first time by the Czochralski technique. Although GdF₃ and YbF₃ both present a high-temperature phase transition, the mixed compound Gd_0.81Yb_0.19F₃ maintains its crystallographic structure upon cooling to room temperature. The grown crystal melts noncongruently at ∼1413 K, it is transparent and colourless, and it has a high density.

The tunnel manganese oxide Na_4.32Mn₉O₁₈: a new Na⁺ site discovered by single-crystal X-ray diffraction

The title compound contains Na⁺ cations within both a six-sided tunnel and a large S-shaped tunnel formed by the manganese oxide framework. The unexpected location of a new Na⁺ site within the S-shaped tunnel accounts for the observation of an Na stoichiometry greater than 4.

1,1′-[(Ethane-1,2-diyldi­oxy)di-o-phenyl­ene]bis­(indoline-2,3-dione) (L) and a novel [Ag₂L₂]²⁺ metallocycle based on coordination-driven Ag—O and Ag—π bonds

(5-tert-Butyl­porphyrinato)copper(II), a nonplanar porphyrin with only one sterically demanding meso residue

Tricarbon­yl(η⁵-cyclo­penta­dien­yl)(tri­fluoro­hydroxy­borato)tungsten

catena-Poly[[bis­(μ-2-sulfonato­benzoato)bis­[tri­aqua­gadolinium(III)]]-μ-oxalato]

Hexa­kis­(urea-κO)zinc(II) dinitrate at 110 and 250 K: uniaxial negative thermal expansion

Poly[μ₃-hydroxido-μ₆-sulfato-μ₃-(1,2,4-triazolato-κ³N¹:N²:N⁴)-dicadmium(II)]: a cadmium–triazolate coordination polymer with a pseudo-cubane-like tetra­nuclear cluster

(6-Oxido-2-oxo-1,2-di­hydro­pyrimidine-5-carboxyl­ato-κ²O⁵,O⁶)bis­[2-(2-pyrid­yl)-1H-benz­imidazole-κ²N²,N³]manganese(II) monohydrate

Poly[di­aqua­bis­(μ-4,4′-bi­pyridine-κ²N:N′)bis­(ethane-1,2-diol)di-μ-sulfato-dicopper(II)]

DL-Alaninium semi-oxalate monohydrate

A structural and theoretical study of inter­molecular inter­actions in nicotinohydrazide di­hydro­chloride

Arcyriaflavin A monohydrate

2-Propynyl 2,3,4,6-tetra-O-acetyl-α-D-manno­pyran­oside

Methyl 2-(4-bromo­phenyl)-1-(5-tert-butyl-1H-pyrazol-3-yl)-1H-benz­imidazole-5-carboxyl­ate: a hydrogen-bonded chain of edge-fused centrosymmetric rings

4-(2,5-Dioxo-2,5-di­hydro-1H-pyrrol-1-yl)benzoic acid: X-ray and DFT-calculated structure

Four stereoisomers of the novel μ-opioid receptor agonist ta­penta­dol hydro­chloride

1,4-Phenyl­enebis(methyl­ene) bis­(9H-carbazole-9-carbodi­thio­ate)

Two 1,4-di­hydro­pyridine derivatives with potential calcium-channel antagonist activity