issue contents
February 2003 issue
inorganic compounds
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The structure of the new compound Li15Al3Si6 is described as consisting of interpenetrating anionic and cationic lattices, namely a graphite-like Li3Al3Si6 layer and a distorted diamond-like lithium lattice.
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Two members of the solid-solution series Ba1−xAl2−2xSi2+2xO8, with x = 0.20 or 0.06, have been synthesized and are shown to have the celsian structure, but with Ba deficiency.
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The crystal structure of LaTiO3.41 consists of (110) perovskite-type slabs with a width of five TiO6 octahedra, which are separated by additional oxygen layers. A superstructure is observed in the [100] direction.
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NaCa4Nb5O17 belongs to the AnBnO3n+2 family. The structure consists of perovskite-related blocks of distorted NbO6 octahedral layers. Na atoms partially replace Ca inside the blocks, but not in the cavities between blocks.
metal-organic compounds
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organic compounds
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