Tetra­aqua­cobalt(II) bis­[vanadyl(IV) phosphate], [Co(H₂O)₄][VO(PO₄)]₂

The structure of [Co(H₂O)₄][VO(PO₄)]₂ consists of vanadyl phosphate layers containing corner-sharing VO₅ square pyramids and PO₄ tetrahedra. These layers are linked by interlayer CoO₆ octahedra into a three-dimensional structure.

Cs[Si₃O₆(OH)] and Rb[Si₂O₄(OH)]: two novel phyl­losilicates

The crystal structures of two novel phyl­losilicates have been characterized by single-crystal X-ray diffraction. The caesium phyl­losilicate has silica sheets composed of four- and six-membered rings whereas the rubidium compound is described by six-membered-ring sheets.

β-Y₂Si₂O₇, a new thortveitite-type compound, determined at 100 and 280 K

The structure of the new synthetic thortveitite-type compound diyttrium disilicate, β-Y₂Si₂O₇, has been determined by single-crystal X-ray diffraction and refined in the C2/m space group at 100 and 280 K.

Tris(3,5-di­methyl-1H-pyrazole-1-thio­carboxamidato-κ²N²,N)­cobalt(III)

A uranyl ion complex of N-methyl-p-tert-butyl­dihomo­ammonio­calix­[4]­arene with di­aqua­dipyridine­lithium as counter-ion

Helical catena-poly[[tris­(1H-benzimidazole-κN³)cobalt(II)]-μ-maleato-κ³O,O′:O′′]

Tris­[di­phenyl(2-pyridyl)­phosphine]-μ₃-iodo-tri-μ₃-sulfido-sulfidotrisilvertungsten di­chloro­methane hemisolvate

Bis­(dicyan­amido)(di­ethyl­enetri­amine-κ³N)copper(II) and (dicyan­amido)(tri­ethyl­enetetr­amine-κ⁴N)copper(II) dicyan­amide

Two isomorphous imidazole (Him) complexes: [MCl₂(Him)₂(H₂O)₂] (M = Co and Ni)

Tris(1,10-phenanthroline)sodium 2,4,6-trimercapto-1,3,5-triazin-1-ide

catena-Poly­[[[(1,10-phenanthroline-κ²N,N′)­manganese(II)]-μ-L-tartrato-κ⁴O¹,O²:O³,O⁴] hexahydrate]

Tetra-μ-chloro-1:2κ⁴Cl;1:3κ⁴Cl-bis­(4,4′-di­methyl-2,2′-bi­pyridine)-2κ²N,3κ²N-lithium(I)­dipalladium(II) tetra­kis­(penta­fluoro­phenyl)­borate di­chloro­methane 1.196-solvate

The iso­thio­cyanate complex of tri­phenyl­borane forms an unusual coordination polymer with [K(18-crown-6)]⁺, both in the solid state and in solution

Bis­(aceto­nitrile-κN)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetra­aza­tetra­decane-κ⁴N]copper(II) bis­{tetra­kis­[3,5-bis­(tri­fluoro­methyl)­phenyl]­borate} 0.31-hydrate

Three yttrium crotonate complexes with di­imines

Potassium 3-cyano-4-(di­cyano­methylene)-5-oxo-4,5-di­hydro-1H-pyrrol-2-olate

[1,3-Bis(4-nitro­phenyl)triazenido](tri­phenylphosphine)gold(I)

Isolated pentaiodide anions in [K(18-crown-6)]I₅

ap-9-(meta-tert-Butyl­phenyl)­fluorene

Ethyl N-phenyl­oxamate

2-Amino-1,3-benzo­thia­zole–ethyl coumarin-3-carboxyl­ate (1/1)

Benzyltri­propylammonium bromide: a structure in polar space group P4₂bc

1,2-Di­nitroguanidine

Bis(glycylglycinium) oxalate at 100 K

C.I. Pigment Red 266

Crystal engineering with heteroboranes. II. 1,2-Di­carb­oxy-1,2-dicarba-closo-dodecaborane(12) ethanol hemisolvate

R(30) rectangular rings in 2,5-dioxopiperazine-1,4-di­acetic acid

Rearrangement products of 3-methane­sulfonyl-N-methyl-N-nitro­aniline

Three polymorphs (α, β, and δ) of D-mannitol at 100 K

Tri­bromo(3,5-di­methyl-2-nitro­phenyl-κ²C¹,O)­tellurium(IV), bromo(3,5-di­methyl-2-nitro­phenyl-κ²C¹,O)­tellurium(II) and bromo(3,5-di­methyl-2-nitro­sophenyl-κ²C¹,O)­tellurium(II)

Pergolide mesyl­ate form II

O-(2-tert-Butyl-6-di­methyl­thio­carbamoyl-4-methylphenyl) N,N-di­methyl­thiocarbamate di­chloro­methane solvate

(–)-2-(1,2,3,4,4a,5,6,7,8,8aα-Deca­hydro-4aβ,8α-di­methyl-7-oxo-2β-naphthyl)propionic acid: catemeric hydrogen bonding in a bicyclic sesquiterpenoid ζ-keto acid

Berberine formate–succinic acid (1/1)

Crystal engineering with heteroboranes. III. 2-Carb­oxy-1-meth­oxymethyl-1,2-dicarba-closo-dodecaborane(12)

L-Me­thionyl-L-alanine: a dipeptide with hexagonal symmetry and Z′ = 7

Dibothrioclinin I and II, epimers from Gerbera piloselloides (L.) Cass

2-Bromo-6-(4,4,5,5-tetra­methyl-1,3,2-dioxaborolan-2-yl)pyridine, a new unexpected bifunctional building block for combinatorial chemistry

Methyl (±)-1-ethyl-2-hy­droxy-4-(4-methoxybenzoyl)-5-(4-methoxyphenyl)-3-oxo-2,3-di­hydro-1H-pyrrole-2-acetate

2-[(2-Hydroxy-4-nitro­phenyl)­amino­methyl­ene]­cyclo­hexa-3,5-dien-1(2H)-one

5-Chloro-2-hydroxybenzo­phenone, featuring O—H⋯O, C—H⋯O, C—H⋯π and π–π interactions