K₄VP₂S₉

The crystal structure of the title compound, prepared by reacting a mixture of K₂S₃, VP, P₄S₃ and S, consists of discrete [VS(PS₄)₂]⁴⁻ anions, which are stacked along the direction of the crystallographic b axis and separated by K⁺ cations. In the anion, the V atom is connected to five S atoms within a square pyramid. The VS₅ group shares common edges with two bidentate [PS₄] tetrahedra.

In_1.06Ho_0.94Ge₂O₇: a thortveitite-type compound

The crystal structure of a new indium holmium germanate, In_1.06Ho_0.94Ge₂O₇, belonging to the thortveitite structure type, is reported. The In³⁺ and Ho³⁺ cations occupy the same octahedral site, forming an hexagonal arrangement on the ab plane. In their turn, the hexagonal arrangements of (In/Ho)O₆ octahedral layers are held together by sheets of isolated diortho groups comprised of double tetrahedra sharing a common vertex.

Cs₂Cr₄O₁₃: a new structure type among alkali tetrachromates

Cs₂Cr₄O₁₃ contains a [Cr₄O₁₃]²⁻ anion with a zigzag-like structure, built from four corner-linked CrO₄ tetrahedra, and has a structure type previously unknown among alkali tetrachromates.

The high-temperature modification of zinc catena-polyphosphate, β-Zn(PO₃)₂

Single crystals of the high-temperature modification of zinc catena-polyphosphate, β-Zn(PO₃)₂, were grown from a melt and quenched from 1093 K to room temperature. The structure is built of corrugated (PO₃)_∞ polyphosphate chains linked by slightly distorted [ZnO₄] tetrahedra into a three-dimensional network.

Poly­[[bis­(1H-benz­imidazole-κN³)cadmium(II)]-μ-aqua-μ-succinato-κ²O¹:O⁴]

An oxo-bridged centrosymmetric tetranuclear titanium compound

A new complex of HgBr₂ and pyrimidine-2-thione: (pyrimidine-2-thionato-κS)(pyrimidinium-2-thionato-κS)mercury(II) tetra­bromomercury(II)

(2,2′-Bi­pyridine-κ²N,N′)(1,1-cyclobutanedi­carboxylato-κ²O,O′)palladium(II), (1,1-cyclo­butanedicarboxylato-κ²O,O′)(1,10-phenanthroline-κ²N,N′)palladium(II) monohydrate and (1,1-cyclo­butanedi­carboxylato-κ²O,O′)(1,10-phenanthroline-κ²N,N′)palladium(II) dihydrate

Bis­[bis­(pyrimidin-2-yl-κN)­amine](dicyan­amido-κN¹)(tri­fluoro­methanesulfonato-κO)copper(II) ethanol hemisolvate forms a hydrogen-bonded chain

Bis­(benzyl­ammonium) hexa­chloro­tin(IV)

[5,10,15,20-Tetra­kis­(penta­fluoro­phenyl)­porphyrinato]­iron(II) benzene disolvate

Tetrameric di­chloro­(tri­methyl­ammonio-p-toluene­sulfonamidate)­mercury(II)

catena-Poly­[bis­[(2,2-bi­pyridine-κ²N,N′)­copper(II)]-μ₄-1,2,4,5-benzene­tetra­carboxyl­ato-κ⁴O¹:O²:O³:O⁴]

Bis­[tris­(2,2′-bi­pyridine-κ²N,N′)­ruthenium(II)] hexa­cyano­ferrate(III) chloride octahydrate

Bis(2,2′-bi­pyridine-κ²N,N′)(1,10-phen­anthroline-κ²N,N′)­ruthenium(II) tetra­cyano­platinate(II)

The Zn²⁺ salt of pamidronate: a role for water in the metal–cation binding properties of bis­phospho­nates

Poly­[lead(II)-μ₂-aqua-μ₄-tereph­thalato]

A novel five-coordinate cadmium phenanthroline thio­sulfate

Chloro{2,2′-[(1S,2S)-1,2-di­phenyl-1,2-ethanediyl­bis­(nitrilo­methyl­idyne)]­diphenolato-κ⁴O,N,N′,O′}(ethanol-κO)­manganese(III)

Tetra-μ-benzoato-κ⁸O:O′-bis­({1-[(3,4-di­meth­oxy­phenyl)­methyl]-6,7-di­meth­oxy­iso­quinoline-κN}­zinc(II)): the first crystal structure with papaverine as a ligand

Diiso­propyl­phosphitocobalamin–acetone–water (1/3.48/7.56)

The di­iso­propyl­phosphite ligand coordinates to the Co^III atom via its P atom. The crystal structure is isomorphous with that of other cobalamins that adopt packing type II, with a Co—P bond length [2.227 (1) Å] similar to that found in other phosphitocobalamins.

A polymeric ladder complex: catena-poly­[[[μ-4,4′-bi­pyridyl-bis­[aqua(p-amino­benzoato)copper(II)]]-di-μ-4,4′-bi­pyridyl] dinitrate tetrahydrate]

Tetra­kis­(tetra­hydro­furan-κO)­lithium mer-tris­(carbazolyl-κN)-trans-di­chloro(tetra­hydro­furan-κO)­zirconate

catena-Poly­[[bis­(hexa­fluoro­acetyl­acetonato-κ²O,O′)­zinc(II)]-μ-4,4′-bi­pyridine-κ²N:N′]

2,4-Di­nitro­phenyl­hydrazones of 2,4-di­hydroxy­benz­aldehyde, 2,4-di­hydroxy­aceto­phenone and 2,4-di­hydroxy­benzo­phenone

5,5′-Di-tert-butyl-2,2′-di­hydroxy-3,3′-methyl­enedibenz­aldehyde and 6,6′-di-tert-butyl-8,8′-methyl­ene­bis­(spiro­[4H-1,3-benzodioxin-2,1′-cyclo­hexane])

16-(4-Iso­propyl­benzyl­idene)­androst-4-ene-3,17-dione

2,2′-Bipyridinium(1+) bromide monohydrate

N¹-(2,6-Di­methyl­phenyl)-N²-hy­droxy-α-oxo-α-phenyl­acet­amidine

N-(2-Fluoro­ethyl)-3β-(4-iodo­phenyl)-8-methyl-8-aza­bicyclo­[3.2.1]­octane-2α-carbox­amide: a new cocaine derivative with equatorially attached ligands

π-Stacked hydrogen-bonded dimers in 2-(2-nitro­phenyl­amino­carbonyl)­benzoic acid, and hydrogen-bonded sheets in orthorhombic and monoclinic polymorphs of 2-(4-nitro­phenyl­amino­carbonyl)­benzoic acid

4-Chloro-N-(tri­methyl­ammonio)­benz­amide chloride monohydrate

Twinning by merohedry in cyclo­hexanone oxime: a revised structure

6-[3-Hy­droxy-17-oxoestra-1,3,5(10)-trien-7β-yl]­hexane­nitrile

4-[(2-Chloro­phenyl)­diazenyl]-6-meth­oxy-2-{[tris­(hy­droxy­methyl)­methyl]­amino­methyl­ene}cyclo­hexa-3,5-dien-1(2H)-one

3-Oxa-6,8-di­aza-1,2:4,5-dibenzocyclo­octa-1,4-dien-7-one: a three-dimensional network assembled by hydrogen-bonding, π–π and edge-to-face interactions

4-Oxo­cyclo­hexane­carboxylic acid: hydrogen bonding in the monohydrate of a δ-keto acid

3-Butyl-1-(5-nitro­benzo­[c][1,2]­thia­zol-3-yl)-3-phenyl­triazene

Monitoring structural transformations in crystals. 7. 1-Chloro­anthracene and its photodimer

tert-Butyl 5-meth­oxy-3-pentyl­indole-1-carboxyl­ate

Two triclinic polymorphs of 2,3,5,6-tetra­kis­(naphthalen-2-yl­sulfanyl­methyl)­pyrazine

sp-9-(o-Methyl­phenyl)­fluorene

An aza-steroidal [17,16-c]­pyrazole derivative: 2′-(p-fluoro­phenyl)-17a-aza-2′H-pyrazolo­[4′,3′:16,17]-D-homoandrost-4-en-3-one

16-Cyano-13α-(5-methyl-1,3,4-oxa­diazol-2-yl)-13,16-seco-17-nor­androst-5-en-3β-yl acetate