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September 2006 issue
inorganic compounds
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The structural data at 163 and 293 K for II-BaB2O4, an excellent non-linear optical material, indicate a significant shortening of the c axial length in the unit cell at 163 K, whereas the a and b axial lengths essentially do not change.
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In Li[VO2(IO3)2], distorted VO6 octahedra are bridged by iodate groups to form two-dimensional [VO2(IO3)2]− layers that are separated by octahedrally coordinated Li+ cations.
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Orthorhombic Mn(SO3)(H2O)3 crystallizes with P212121 symmetry, as determined by the H-atom positions and the hydrogen-bond network.
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In addition to the spinel-type 16d and 8a positions of space group Fdm, a small fraction of the Al ions in γ-alumina also occupy the non-spinel 6c and 48f positions.
metal-organic compounds
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The title compound crystallizes in P21/a with all the atoms located in general positions. The trichlate anion consists of pyramidal SO3 and CCl3 groups connected via an S—C bond in a staggered conformation with approximate C3v symmetry.
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organic compounds
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