issue contents
April 2008 issue
inorganic compounds
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The Cu6P(Se0.7S0.3)5Br cubic structure is built from a [P(Se0.7S0.3)5Br] framework in which CuI ions are distributed in various tetrahedral, triangular and linear sites. The compound is a solid solution of two efficient ionic conductors, namely Cu6PSe5Br and Cu6PS5Br, in which high ionic conductivity results from order–disorder phenomena in the copper substructure.
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The crystal structure of K2[O(HgSO3)3] features a layered assembly of K+ cations and complex [O(HgSO3)3]2− anions with m symmetry and a slightly distorted trigonal–pyramidal OHg3 core.
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The title compound contains a unique framework of LiO4 and VO4 tetrahedra, which are linked to produce porous double layers separated along the c direction by isolated chains of face-sharing LiCl6 octahedra. Within the layers, six-tetrahedron Li2V4O18 rings form large channels filled by Ba2+ and Cl− ions.
metal-organic compounds
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organic compounds
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