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October 2012 issue
inorganic compounds
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The crystal structure of the cubic compound Ni2Sn2Zn is related to that of Ni5.20Sn8.7Zn4.16Cu1.04 and shows common structural elements with the atomic arrangements of the high-temperature phase of Ni3Sn2 and with Ni5Sn4Zn. It exhibits a considerable homogeneity range, along with mixed occupations and partially occupied sites.
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The title compound, [Te8][NbOCl4]2, crystallizes with triclinic lattice symmetry and consists of infinite {[Te8]2+}n cations associated with pyramidal [NbOCl4]− anions. The novel catena-octatellurium(2+) cation is composed of Te5 rings that are linked via Te3 units.
metal-organic compounds
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organic compounds
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