issue contents
May 2011 issue
inorganic compounds
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The title compound exhibits a three-dimensional framework, which is composed of a distinct eight-coordinated DyIII centre together with μ4-sulfate and μ4-sulfite multidentate bridging ligands. The water molecules around the metal centre are stabilized by hydrogen bonds.
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A new ferric sulfate trihydrate has been synthesized at 403 K under hydrothermal conditions. The structure consists of quadruple chains of [Fe2(SO4)3(H2O)3] parallel to [010]. Each quadruple chain is composed of equal proportions of FeO4(H2O)2 octahedra and FeO5(H2O) octahedra sharing corners with SO4 tetrahedra. The chains are joined to each other by hydrogen bonds.
metal-organic compounds
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organic compounds
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