Nonasodium Bis(hexa­hydroxoaluminate) Tri­hydroxide Hexahydrate

The Al atoms in Na₉[Al(OH)₆]₂(OH)₃.6H₂O have octahedral coordination geometry and exist as monomeric [Al(OH)₆]³⁻ anions. The Na⁺ ions also have octahedral coordination geometry and are coordinated by OH⁻ ions and water molecules. The NaO₆ octahedra are linked through common edges, incorporating the [Al(OH)₆]³⁻ octahedra, to yield a three-dimensional network.

A New Synthetic Fluoride Phosphate of Mixed-Valence Iron: Cs₈Fe₈³⁺Fe₇²⁺F₁₀(PO₄)₁₂

The orthophosphate Cs₈Fe₁₅F₁₀(PO₄)₁₂ is built from layers of vertex-sharing Fe polyhedra linked into a framework by PO₄ tetrahedra. The Fe³⁺ ions have octahedral coordination geometry and the Fe²⁺ ions have octahedral, tetrahedral and distorted tetragonal pyramidal coordination environments.

Tri­aquahexa­thio­cyanatobismuthlanthanum Dihydrate, [Bi(SCN)₆La(H₂O)₃].2H₂O, and Tri­aquahexa­thio­cyanatobismuthneodymium Dihydrate, [Bi(SCN)₆Nd(H₂O)₃].2H₂O

The three-dimensional polymeric complexes [Bi(SCN)₆La(H₂O)₃].2H₂O and [Bi(SCN)₆Nd(H₂O)₃].2H₂O are isomorphic with and have a similar structure to the LaFe(CN)₆.5H₂O structure type. The bond lengths in the coordination polyhedra and the hydrogen bonding in the structures are discussed.

Octacaesium Decatungstosilicate Nonahydrate

Cs₈[SiW₁₀O₃₆].9H₂O contains the heteropolyoxometalate anion γ-[SiW₁₀O₃₆]⁸⁻. The polyanions are connected by Cs⁺ ions to form infinite columns.

Ba₃Ga₂N₄

Barium gallium nitride, Ba₃Ga₂N₄, is isostructural with Sr₃Al₂N₄. The structure contains GaN₄ tetrahedra which share edges to form infinite [GaN_4/2³⁻] chains.

Cobalt Silicon Diphosphate, Co₂Si(P₂O₇)₂

The structure of Co₂Si(P₂O₇)₂ contains SiO₄ tetrahedra, eclipsed P₂O₇ groups [with a P-O-P angle of 132.3(1)°] and compressed CoO₆ octahedra. The CoO₆ octahedra share edges to form Co₂O₁₀ units, which are linked via four vertices to form a two-dimensional network.

trans-Tetra­carbonylbis(tri­cyclo­hexylphosphine)molybdenum(0), trans-[Mo(CO)₄(PCy₃)₂]

Bis[μ-bis­(di­phenylphosphino)hexane-P:P']digold(I) Hexa­fluoro­antimonate Aceto­nitrile Solvate

2-Ferrocenyl-3-phenylquinoxaline

1-Ferrocenyl-2-phenylethanedione

Racemic Bis(1-ferrocenylpropyl) Ether

[Mn₄^III(μ₃-O)₂(μ-O₂CMe)₇(2,2'-bi­pyridine)₂]ClO₄

Two Different Crystal Forms of cis-diamminebis(pyrazole)platinum(II) Nitrate

Di-(μ-pyrazolato-N:N')-bis­[(2,2'-bi­pyridine-N,N')platinum(II)] Bis(tetra­fluoroborate) Monohydrate

Dimeric Aqua(3,5-di­nitrobenzoato)(tri­ethylene glycol)calcium(II) 3,5-Di­nitrobenzoate Hydrate

Bis(tri­ethanolamine)calcium 3,5-Di­nitrobenzoate

{Ca(OH₂)₃[Ca(DOTA)].7.7H₂O}_n

The Polymeric Cluster Complex {[(CH₃CH₂)₃NH][WAgS₄].(DMF)}_n

trans-[Mo(CO)₄{P(OMe)₃}₂]

[Pt(PMe₃)₂(dppm)]Cl₂.2H₂O [dppm = Bis(di­phenylphosphino)methane]

A Manganese Quinaldinate Complex: trans-[Di­aquabis(2-quinoline­carboxylato)manganese(II)]–Water–Ethanol (1/2/2)

Dimeric Iodo[1,1-di(2-pyridyl)-3-butenolato]copper(II) Bis(aceto­nitrile) Solvate, [Cu₂(C₁₄H₁₃N₂O)₂I₂].2CH₃CN

Diperchlorato[(1RS,4RS,5SR,7RS,8SR,11SR,12RS,14SR)-(5,7,12,14-tetra­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane)]copper(II)

Di­chlorobis(nicotinamide-N¹-acetate-O)zinc(II)

Di­aqua(2-ethylphenyliminodi­acetato-N,O,O')zinc(II)

Tri­methyloxo­sulfonium Salts. IX. Study of some Mixed Compounds, (CH₃)₃SOCdCl_3−xBr_x

Verfeinerung von Quecksilberdiiodid-(18-Krone-6), Hg(18-krone-6)I₂

cis-Di­aquabis(1,10-phenanthroline-N,N')zinc(II) (1,10-Phenanthroline-N,N')bis­(thio­sulfato-S)zincate(II) Monohydrate

The Five-Coordinate Cadmium Halide Bis(di­ethyldi­thiocarbamate) Complexes [PPh₄][Cd(S₂CNEt₂)₂Cl] and [PPh₄][Cd(S₂CNEt₂)₂Br]

(Di­methyl sulfoxide-S)methyl(1,10-phenanthroline-N,N')platinum(II) Hexa­fluorophosphate

Poly[trans-bis­{tri­methyltin(IV)}-μ-(2,2'-bi­pyridyl-4,4'-di­carboxylato-O:O':O'':O''')]. A Layered Structure Composed of Sheets Interconnected by Organometallic Moieties

μ-Oxo-bis­[(5,10,15,20-tetra­phenylporphyrinato)oxomolybdenum(V)]

A Trinuclear Cluster of Molybdenum(IV), Mo₃(μ₃-S)(μ₂-S)₃(HC₂O₄)₂(C₂O₄)(H₂O)₃

(meso-4,8-Di­aza-3,9-di­methyl-6,6-tri­methyleneundecane-2,10-dione dioximato-N,N',N'',N''')oxotechnetium(V), [TcO(C₁₄H₂₅N₄O₂)]

[Fe₂(CO)₄(PMe₃)₄(μ-H)(μ-SiCl₂)][Fe(CO)₄(SiCl₃)]

(N-Pyrrolidinecarbodi­thioato-S,S')bis­(tri­phenylphosphine)silver(I)

Bis(O-cyclo­hexyl di­thiocarbonato)di­methyltin(IV)

Low-Temperature Structures of fac-Tri­chloro(tetra­hydro­furan)(D, L-tetra­hydrofurfuranol)titanium(III) and fac-Tri­chloro(tetra­hydro­furan)(D, L-tetra­hydrofurfuroxide)titanium(IV)

[Bis(di­phenylphosphino)amine-P,P']bromotri­carbonylrhenium(I), [ReBr(CO)₃{NH(PPh₂)₂}]

1-Carbonyl-2,2-cis-di­carbonyl-μ-formato-1C:2O,O'-1-nitrosyl-1-(η⁵-penta­methylcyclo­pentadienyl)-2,2-trans-bis­(tri­phenylphosphine)dirhenium

Two `Ruthenium-Blue' Precursors: Tri-μ-chloro-hexa­kis­(di­methylphenylarsine)diruthenium(II) Tri­fluoro­methane­sulfonate and Tri-μ-bromo-hexa­kis­(tri­methylarsine)diruthenium(II) Tri­fluoro­methane­sulfonate

Tris(4,4'-bi­pyrimidine)ruthenium(II) Bis(hexa­fluorophosphate) Acetone Solvate

fac-Tri­carbonyldi­chloro(tetra­hydro­furan)ruthenium(II)

Tetra­phenylphosphonium trans-Aqua­tetra­bromo(carbonyl)osmate(III), trans-[(C₆H₅)₄P][OsBr₄(CO)(H₂O)]

Di­aquabis(4-amino-3-methyl-4,5-di­hydro-1H-1,2,4-triazole-5-thione)nickel(II) Nitrate: a Sulfur–Nitrogen Chelate

A Second Polymorph of 2,2'-Bi­pyridyl(methyl)(phenyl)palladium(II)

Di-μ-phosphinato-bis­[(1,10-phenanthroline)copper(II)] Nitrate, [Cu₂(H₂PO₂)₂(phen)₂](NO₃)₂

Chloro{2-[2-(di­methylamino)ethylimino­methyl]phenol}tri­phenyltin(IV) Benzene Hemisolvate, [SnCl(C₆H₅)₃(C₁₁H₁₆N₂O)].0.5C₆H₆

Bis(tri­phenylphosphine)iminium Nitrito(phthalocyaninato)zincate Hydrate

Palladium Complexes of 1,4,7-Tri­thia­cyclo­decane

Di­ethylgallium Di­phenylphosphinate

Iodotris(tri­phenylphosphine)silver(I), [Ag(PPh₃)₃I]

Tetra­kis­(3-methylpyridine)-1κN,2κN,3κN,4κN-bis­(μ₄-penta­thio)-1:2κ²S¹,2κS⁴,3κS²,3:4κ²S⁵;1κS^4',1:3κ²S^1',2:4κ²S^5',4κS^2'-tetracopper(I) Bis(3-methylpyridine) Solvate

Tri­phenylstibine Di­hydroxide

Low-Temperature Structure of Two Copper-Based Precursors for MOCVD: Aquabis(tert-butyl aceto­acetato)copper(II) and Bis(dipivaloylmethanido)copper(II)

Two Diastereomers of Benzyl­idene-D-erythronolactone

7-Amino-3-phenylcoumarin

Absolute Configuration of D-Brompheniramine Maleate

Clemizole Hydrochloride

2,3-Bis(ethylsulfonyl)benzo[b]thiophene

Fluorene-1-carboxylic Acid

An Unusual C(sp²)—H⋯Cl Interaction in the Solid State: Reinvestigation of 4,6-Di­methylpyrimidine-2-thione Hydrochloride Monohydrate

Structures of Five ω-Phthalimidoaliphatic Carboxylic Acids

Structures of Four p-Amidoperbenzoic Acids