Nonasodium Bis(hexa­hydroxoaluminate) Tri­hydroxide Hexahydrate

The Al atoms in Na₉[Al(OH)₆]₂(OH)₃.6H₂O have octahedral coordination geometry and exist as monomeric [Al(OH)₆]³⁻ anions. The Na⁺ ions also have octahedral coordination geometry and are coordinated by OH⁻ ions and water molecules. The NaO₆ octahedra are linked through common edges, incorporating the [Al(OH)₆]³⁻ octahedra, to yield a three-dimensional network.

A New Synthetic Fluoride Phosphate of Mixed-Valence Iron: Cs₈Fe₈³⁺Fe₇²⁺F₁₀(PO₄)₁₂

The orthophosphate Cs₈Fe₁₅F₁₀(PO₄)₁₂ is built from layers of vertex-sharing Fe polyhedra linked into a framework by PO₄ tetrahedra. The Fe³⁺ ions have octahedral coordination geometry and the Fe²⁺ ions have octahedral, tetrahedral and distorted tetragonal pyramidal coordination environments.

Tri­aquahexa­thio­cyanatobismuthlanthanum Dihydrate, [Bi(SCN)₆La(H₂O)₃].2H₂O, and Tri­aquahexa­thio­cyanatobismuthneodymium Dihydrate, [Bi(SCN)₆Nd(H₂O)₃].2H₂O

The three-dimensional polymeric complexes [Bi(SCN)₆La(H₂O)₃].2H₂O and [Bi(SCN)₆Nd(H₂O)₃].2H₂O are isomorphic with and have a similar structure to the LaFe(CN)₆.5H₂O structure type. The bond lengths in the coordination polyhedra and the hydrogen bonding in the structures are discussed.

Octacaesium Decatungstosilicate Nonahydrate

Cs₈[SiW₁₀O₃₆].9H₂O contains the heteropolyoxometalate anion γ-[SiW₁₀O₃₆]⁸⁻. The polyanions are connected by Cs⁺ ions to form infinite columns.

Ba₃Ga₂N₄

Barium gallium nitride, Ba₃Ga₂N₄, is isostructural with Sr₃Al₂N₄. The structure contains GaN₄ tetrahedra which share edges to form infinite [GaN_4/2³⁻] chains.

Cobalt Silicon Diphosphate, Co₂Si(P₂O₇)₂

The structure of Co₂Si(P₂O₇)₂ contains SiO₄ tetrahedra, eclipsed P₂O₇ groups [with a P-O-P angle of 132.3(1)°] and compressed CoO₆ octahedra. The CoO₆ octahedra share edges to form Co₂O₁₀ units, which are linked via four vertices to form a two-dimensional network.

trans-Tetra­carbonylbis(tri­cyclo­hexylphosphine)molybdenum(0), trans-[Mo(CO)₄(PCy₃)₂]

Bis[μ-bis­(di­phenylphosphino)hexane-P:P']digold(I) Hexa­fluoro­antimonate Aceto­nitrile Solvate

2-Ferrocenyl-3-phenylquinoxaline

1-Ferrocenyl-2-phenylethanedione

Racemic Bis(1-ferrocenylpropyl) Ether

[Mn₄^III(μ₃-O)₂(μ-O₂CMe)₇(2,2'-bi­pyridine)₂]ClO₄

Two Different Crystal Forms of cis-diamminebis(pyrazole)platinum(II) Nitrate

Di-(μ-pyrazolato-N:N')-bis­[(2,2'-bi­pyridine-N,N')platinum(II)] Bis(tetra­fluoroborate) Monohydrate

Dimeric Aqua(3,5-di­nitrobenzoato)(tri­ethylene glycol)calcium(II) 3,5-Di­nitrobenzoate Hydrate

Bis(tri­ethanolamine)calcium 3,5-Di­nitrobenzoate

{Ca(OH₂)₃[Ca(DOTA)].7.7H₂O}_n

The Polymeric Cluster Complex {[(CH₃CH₂)₃NH][WAgS₄].(DMF)}_n

trans-[Mo(CO)₄{P(OMe)₃}₂]

[Pt(PMe₃)₂(dppm)]Cl₂.2H₂O [dppm = Bis(di­phenylphosphino)methane]

A Manganese Quinaldinate Complex: trans-[Di­aquabis(2-quinoline­carboxylato)manganese(II)]–Water–Ethanol (1/2/2)

Dimeric Iodo[1,1-di(2-pyridyl)-3-butenolato]copper(II) Bis(aceto­nitrile) Solvate, [Cu₂(C₁₄H₁₃N₂O)₂I₂].2CH₃CN

Diperchlorato[(1RS,4RS,5SR,7RS,8SR,11SR,12RS,14SR)-(5,7,12,14-tetra­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane)]copper(II)

Di­chlorobis(nicotinamide-N¹-acetate-O)zinc(II)

Di­aqua(2-ethylphenyliminodi­acetato-N,O,O')zinc(II)

Tri­methyloxo­sulfonium Salts. IX. Study of some Mixed Compounds, (CH₃)₃SOCdCl_3−xBr_x

Verfeinerung von Quecksilberdiiodid-(18-Krone-6), Hg(18-krone-6)I₂

cis-Di­aquabis(1,10-phenanthroline-N,N')zinc(II) (1,10-Phenanthroline-N,N')bis­(thio­sulfato-S)zincate(II) Monohydrate

The Five-Coordinate Cadmium Halide Bis(di­ethyldi­thiocarbamate) Complexes [PPh₄][Cd(S₂CNEt₂)₂Cl] and [PPh₄][Cd(S₂CNEt₂)₂Br]

(Di­methyl sulfoxide-S)methyl(1,10-phenanthroline-N,N')platinum(II) Hexa­fluorophosphate

Poly[trans-bis­{tri­methyltin(IV)}-μ-(2,2'-bi­pyridyl-4,4'-di­carboxylato-O:O':O'':O''')]. A Layered Structure Composed of Sheets Interconnected by Organometallic Moieties

μ-Oxo-bis­[(5,10,15,20-tetra­phenylporphyrinato)oxomolybdenum(V)]

A Trinuclear Cluster of Molybdenum(IV), Mo₃(μ₃-S)(μ₂-S)₃(HC₂O₄)₂(C₂O₄)(H₂O)₃

(meso-4,8-Di­aza-3,9-di­methyl-6,6-tri­methyleneundecane-2,10-dione dioximato-N,N',N'',N''')oxotechnetium(V), [TcO(C₁₄H₂₅N₄O₂)]

[Fe₂(CO)₄(PMe₃)₄(μ-H)(μ-SiCl₂)][Fe(CO)₄(SiCl₃)]

(N-Pyrrolidinecarbodi­thioato-S,S')bis­(tri­phenylphosphine)silver(I)

Bis(O-cyclo­hexyl di­thiocarbonato)di­methyltin(IV)

Low-Temperature Structures of fac-Tri­chloro(tetra­hydro­furan)(D, L-tetra­hydrofurfuranol)titanium(III) and fac-Tri­chloro(tetra­hydro­furan)(D, L-tetra­hydrofurfuroxide)titanium(IV)

[Bis(di­phenylphosphino)amine-P,P']bromotri­carbonylrhenium(I), [ReBr(CO)₃{NH(PPh₂)₂}]

1-Carbonyl-2,2-cis-di­carbonyl-μ-formato-1C:2O,O'-1-nitrosyl-1-(η⁵-penta­methylcyclo­pentadienyl)-2,2-trans-bis­(tri­phenylphosphine)dirhenium

Two `Ruthenium-Blue' Precursors: Tri-μ-chloro-hexa­kis­(di­methylphenylarsine)diruthenium(II) Tri­fluoro­methane­sulfonate and Tri-μ-bromo-hexa­kis­(tri­methylarsine)diruthenium(II) Tri­fluoro­methane­sulfonate

Tris(4,4'-bi­pyrimidine)ruthenium(II) Bis(hexa­fluorophosphate) Acetone Solvate

fac-Tri­carbonyldi­chloro(tetra­hydro­furan)ruthenium(II)

Tetra­phenylphosphonium trans-Aqua­tetra­bromo(carbonyl)osmate(III), trans-[(C₆H₅)₄P][OsBr₄(CO)(H₂O)]

Di­aquabis(4-amino-3-methyl-4,5-di­hydro-1H-1,2,4-triazole-5-thione)nickel(II) Nitrate: a Sulfur–Nitrogen Chelate

A Second Polymorph of 2,2'-Bi­pyridyl(methyl)(phenyl)palladium(II)

Di-μ-phosphinato-bis­[(1,10-phenanthroline)copper(II)] Nitrate, [Cu₂(H₂PO₂)₂(phen)₂](NO₃)₂

Chloro{2-[2-(di­methylamino)ethylimino­methyl]phenol}tri­phenyltin(IV) Benzene Hemisolvate, [SnCl(C₆H₅)₃(C₁₁H₁₆N₂O)].0.5C₆H₆

Bis(tri­phenylphosphine)iminium Nitrito(phthalocyaninato)zincate Hydrate

Palladium Complexes of 1,4,7-Tri­thia­cyclo­decane

Di­ethylgallium Di­phenylphosphinate

Iodotris(tri­phenylphosphine)silver(I), [Ag(PPh₃)₃I]

Tetra­kis­(3-methylpyridine)-1κN,2κN,3κN,4κN-bis­(μ₄-penta­thio)-1:2κ²S¹,2κS⁴,3κS²,3:4κ²S⁵;1κS^4',1:3κ²S^1',2:4κ²S^5',4κS^2'-tetracopper(I) Bis(3-methylpyridine) Solvate

Tri­phenylstibine Di­hydroxide

Low-Temperature Structure of Two Copper-Based Precursors for MOCVD: Aquabis(tert-butyl aceto­acetato)copper(II) and Bis(dipivaloylmethanido)copper(II)

Two Diastereomers of Benzyl­idene-D-erythronolactone

7-Amino-3-phenylcoumarin

Absolute Configuration of D-Brompheniramine Maleate

Clemizole Hydrochloride

2,3-Bis(ethylsulfonyl)benzo[b]thiophene

Fluorene-1-carboxylic Acid

An Unusual C(sp²)—H⋯Cl Interaction in the Solid State: Reinvestigation of 4,6-Di­methylpyrimidine-2-thione Hydrochloride Monohydrate

Structures of Five ω-Phthalimidoaliphatic Carboxylic Acids

Structures of Four p-Amidoperbenzoic Acids

2-(2-Aminophénylthio)-2-(2-thiényl)éthyl 2-Thiényl Cétone

2',6'-Di­hydroxyflavone and a New Polymorph of 2'-Hydroxyflavonol

2-(2-Amino-5-bromo­benzoyl)pyridine

Bis(di­phenylphosphino)methane Di­sulfide

Absolute Configuration of 6-O-p-Bromo­benzoylsalvileucolide Methyl Ester

Arene–Arene Stacking in 6,6'-Di­phenyl-3,3'-bi-1,2,4,5-tetrazine and 6-Phenyl-1,2,4,5-tetrazine-3-carbaldehyde Benzoylhydrazone Monohydrate

3-Amino-4-hydroxybenzene­sulfonic Acid Hemihydrate

A Photoproduct Derived from 9-Benzyl-Substituted Dibenzobarrelene

1-Iodo-2-meth­oxy-7-naphthyl Acetate

trans-1,1'-Bis(indenyl­idene)

N,N-Bis(2-hydroxybenzyl)-N-(2-pyridylmethyl)amine, H₂BBPA

Triclinic Form of Dipyrrolidinylthiuram Di­sulfide

(S)-1-Acetoxymethyl-2-acetyl-1,2,3,4-tetra­hydro-6,7-di­meth­oxy-1-methyliso­quinoline

2-(2-Pyridyl)pyridinium Triiodide

4-Methylbenzylammonium 4-Methylbenzylcarbamate

2,8-Di­methyl-5,11-di­propyl-1,4,5,6,7,10,11,12-octa­hydroimidazo[4,5-h]imidazo[4,5-c][1,6]diazecine Hexahydrate

3-(6-Meth­oxy-2-benzimidazolyl)benzo­thiazolin-2-imine

N,N-Di­methyl-2,4-di­nitroaniline

Energetic Materials: the Biguanidium Nitrates

5,6,7,8-Tetra­hydro-2,3-di­phenyl-2aλ⁴-thia-2,3,4a,8a-tetra­aza­cyclopent[cd]azulene-1[2H],4[3H]-diselone

Three Protected Tetrapeptides

4-tert-Butyloxycarbonyl-6(S)-(hydroxymethyl)-3(S)-(1-methylethyl)piperazin-2-one

1,4-Di­bromo-1,4-disila­butane

5-Amino-1,2-di­methylimidazole

A Photochromic Zwitterionic Viologen: 4,4'-Bipyridinium-1,1'-bis­(2-ethylsulfonate) Monohydrate

p-Methoxybenzaldehyde Nicotinoylhydrazone Dihydrate

(2R,3R)-3-Ammonio-1-(1-methoxycarbonyl-2-methyl-1-propenyl)-4-oxoazetidine-2-sulfonate Monohydrate: a New Chiral β-Lactam Synthon

5,10-Di­iodo-5,10-di­hydroboranthrene

cis-1,5-Di­methyl-2,4-di­nitro-2,4-di­azabi­cyclo[3.2.0]heptan-3-one and cis-1,5-Di­methyl-2,4-di­nitro-2,4-di­azabi­cyclo[3.1.0]hexan-3-one

7-Benzyl-3-thia-7-azabi­cyclo[3.3.1]nonane 3-Oxide

2-Aminoperimidinium Bromide Dihydrate

1-(4-Nitro­phenyl)-4-piperidinol

Identification of the N-Alkylation Product of 3-(2-Pyrrolyl)pyridazine

Trichotomine Di­methyl Ester

5-Cyclo­hexylamino-2-phenyl-4-thiazolecarbo­nitrile

Bis(4-methoxyphenyl)methano[60]fullerene with a Methano Bridge at the 6–6-Ring Junction

3-Cyano-1-[4-(1,3-di­thian-2-yl)butyl]-1,4,5,6-tetra­hydro­pyridine

1-Cyano­methyl-6,7,8-trioxabi­cyclo[3.2.1]octane

Two Schiff Base Ligands Derived from 1,2-Di­amino­cyclo­hexane

8-Hy­droxy-7-nitro­quinoline-5-sulfonic Acid Monohydrate

A Non-Peptide Angiotensin II Receptor Antagonist: 2-Butyl-6-di­methoxymethyl-5-phenyl-1-{[2'-(1H-tetrazol-5-yl)bi­phenyl-4-yl]methyl}-1H-imidazo[5,4-b]pyridine

Ipriflavone, an Antiostheophorotic Agent

A New Crystalline Form of 1-Phenyl-1,2-dicarba-closo-dodecaborane(12)

2,2'-Piperazin-1,4-diyldi­methylenebis[6-(benzylimino­methyl)-4-methylphenol]

(1RS,4aSR,12aSR)-1-Methyl-1,2,3,4,4a,5,6,7,12,12a-deca­hydrodibenzo[a,d]cyclooctene-1,4a-carbolactone

7-Ethoxycarbonylmethyl-5-methyl-1,2,4-triazolo[1,5-a]pyrimidine

An MPP⁺ Analog: the 2:1 N-Cyclo­pentyl-4-phenylpyridinium Bromide–4-Phenylpyridine Complex

4-[(1-Cyclohexenyl)nitro­methyl]-2-(3,4-methylene­dioxyphenyl)-3-nitro-3,4-di­hydro-2H-1-benzo­pyran

X-ray Structure Investigations of Potential β-Blockers. II. 6,7-Di­meth­oxy-1-phenyl-1,2,3,4-tetra­hydroiso­quinoline

2-Amino-4-nitrobenzo­thiazole

Tarapacol 15-Acetate, a New Diterpenoid from Grindelia tarapacana Phil.

Absolute Configuration of (S)-(+)-[(Benzyloxymethyl)(tert-butyl)methylsilyl] Methyl Ketone

Two Energetic Ionic Materials: the Biguanidium Perchlorates

8-(3-Methylphen­oxy)-16H-di­naphtho[2,1-d;1',2'-g][1,3,2]dioxa­phosphocine 8-oxide

2,4-Pentanedione Bis(2,4-di­nitro­phenylhydrazone)

1-(2,4-Di­nitro­phenyl)-3,5-di­methylpyrazole

3-Hy­droxy-6-methyl-2-pyridylmethyl Iso­propylphosphonate Sesquihydrate