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January 2003 issue
editorial
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international union of crystallography
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inorganic compounds
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In the title compound, the NiII cations have a pseudo-face-centered cubic cell, with cell parameter a 10.216 Å and tetrahedral cavities occupied by P atoms. The NiII cation has an octahedral coordination sphere consisting of six water O atoms. The planes of oppositely coordinated water molecules are in a cross conformation. The geometry of the hypophosphite anion is close to point symmetry mm2. The hypophosphite anions are hydrogen bonded to the coordinated water molecules.
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Single crystals of lithium niobium disulfide, prepared by separated reactant metathesis, yielded a refined Li content of y = 0.63 (6). The Li content has been further confirmed analytically both by flame photometry and by preliminary neutron powder diffraction data.
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The structure of UO2(NO3)2(H2O)3 consists of two distinct centrosymmetric isolated hexagonal uranyl bipyramids, which share edges with two nitrate groups. Water is structurally located in the interstices between these isolated uranyl dinitrate clusters and at the equatorial edges of the [UO2(NO3)2] groups.
metal-organic compounds
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organic compounds
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