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March 2003 issue
inorganic compounds
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The single-crystal structure of potassium manganese tris[dicyanoargentate(I)], KMnAg3(CN)6, is described. This is the first Mn-containing example of the triply interpenetrating MAg3(CN)6 type. The K+ ion is found to be located in an ordered manner on one of two possible interstitial sites, leading to a chiral space group.
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Substitution of Cl by Br atoms into the known structure of SrCd2Cl6·8H2O leads to a disappearance of the twin phenomenon previously observed and a new arrangement of the Sr(H2O)9 polyhedra in chains by the sharing of bases of the triangular prisms.
metal-organic compounds
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organic compounds
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