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September 2008 issue
inorganic compounds
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The crystal structure of hydrothermally grown CaTe2O5 is made up of undulating 2∞[Te2O5]2− layers propagating parallel to (100) with the TeIV atoms in fourfold coordination. Adjacent layers are linked by distorted [CaO7] polyhedra along [100].
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The title compounds belong to the apatite family. Suitable single crystals were prepared under hydrothermal conditions. All three structures consist of isolated slightly distorted AsO4 tetrahedra which are bridged by Sr2+ in Sr5(AsO4)3F, by Sr2+/Ba2+ in (Sr1.66Ba0.34)(Ba2.61Sr0.39)(AsO4)3Cl and by Cd2+ in Cd5(AsO4)3Cl0.58(OH)0.42.
metal-organic compounds
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organic compounds
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