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December 2005 issue
inorganic compounds
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Rietveld refinement using powder neutron diffraction data shows that the structure of Tl2BeF4, from room temperature to 1.5 K, belongs to the orthorhombic space group Pnma, without evidence of any phase transition.
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The structure of K2Cr4O13 is built up from isolated zigzag [Cr4O13]2− units with intercalated potassium ions.
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The isotypic orthorhombic dihydrogendiphosphates K2M(H2P2O7)2·2H2O (M = Ni, Cu, Zn) contain octahedrally coordinated M2+ cations in M(H2P2O7)2·2H2O units connected by K—O bonds and hydrogen bonds.
metal-organic compounds
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Bis(methylammonium) octaantimony(III) dodecasulfide persulfide, (CH3NH3)2[Sb8S12(S2)], contains pairs of [Sb4S7]2− chains joined through an unusual persulfide bond to create infinite double [Sb2S14]2− chains. The double chains contain (Sb8S10) apertures, in which methylammonium cations, formed by decomposition of 2-methylpropane-1,2-diamine during the synthesis, are located.
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organic compounds
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