Thio­cyanates of nickel and caesium: Cs₂NiAg₂(SCN)₆·2H₂O and CsNi(SCN)₃

The title compounds are the first thio­cyanates to contain both nickel and caesium.

Lithium vanadate Li_3+xV₆O₁₃ at low temperature

The formation of a superstructure and the disorder of Li⁺ ions in the low-temperature phase of Li_3+xV₆O₁₃ [x = 0.24 (3)] are described on the basis of single-crystal X-ray data collected at 95 K.

Rubidium metaborate, Rb₃B₃O₆

The title compound was obtained by the reaction of Rb₂CO₃ and BN using a radiofrequency furnace at a maximum reaction temperature of 1173 K. The crystal structure has been determined by single-crystal X-ray diffraction.

Bis­[benzidinium(1–)] pentamolybdate

Bis­[tris­(ethyl­enedi­amine)­cobalt(III)] di­chloro­bis­[μ-(1-hy­droxy­ethyl­idene)­diphospho­nato(4–)]­diruthenium(II,­III)­(Ru–Ru) chloride trihydrate

Bis­[tris­(pyridin-2-yl)­methanol-κ²N,N′]palladium(II) dinitrate at 150 and 298 K

A novel Na–O–Ni–O–Ni bridging complex of Cl-HXTA, where Cl-HXTA is 2,6-bis­{[bis­(carboxyl­ato­methyl)­amino]­methyl}-4-chloro­phenolate

Bis­[tris­(1-methyl-1H-imidazol-2-yl)­phosphine-κ³N³]­iron(II) tetra­chloro­ferrate(II) methanol tetrasolvate (ca 153 K) and bis­[tris­(1-methyl-1H-imidazol-2-yl)­methanol-κ³N³]­iron(III) bis­[tetra­chloro­ferrate(III)] chloride (redetermination, ca 153 K)

Di­chloro­(methanol-κO)[(meth­oxy)tris­(1-methyl-1H-imidazol-2-yl)­methane-κ²N³]­iron(II) (ca 153 K)

Tris­[bis­(1-methyl-1H-imidazol-2-yl)­methanone-κ²N³]­iron(II) dichloride 5.5-hydrate, cis-bis­[bis­(1-methyl-1H-imidazol-2-yl)­methanone-κ²N³]di­chloroiron(II) (ca 153 K) and di-μ-chloro-bis­{[bis­(1-methyl-1H-imidazol-2-yl)­methanone-κ²N³]­chloroiron(II)} methanol disolvate (ca 300 K)

Di­acetato-κ²O-bis­[(S)-1-(4-fluorophenyl)­ethyl­amine-κN]­palladium(II) and di-μ-acetato-κ⁴O:O′-bis­{[(S)-2-(1-amino­ethyl)-5-fluoro­phenyl-κ²C¹,N]­palladium(II)} benzene hemisolvate

Carbonyl(5-nitrotropolonato-κ²O¹,O²)(tri­phenyl­phosphine-κP)­rhodium(I)

Potassium p-nitro­phenyl sulfate

Iodo­[phthalocyaninato(2–)]­manganese(III) bridged by a neutral I₂ mol­ecule

Bis(2-methyl­imidazolium) hydroxodiphosphatoaluminium

Di­aqua­bis­(pyridine-2-carbox­amide-κ²N¹,O²)­nickel(II) disaccharinate tetrahydrate

Bis(μ-6-hy­droxy­picolinato)-μ-oxo-bis­[di­pyridine­manganese(III)] monohydrate

[Cu(C₈H₁₆N₄O₂)_0.5{N(CN)₂}]_n, a novel ladder-like coordination polymer

Bis­[N,N′-bis­(di­phenyl­methyl­ene)ethyl­enedi­amine-κ²N,N′]copper(I) di­chloro­cuprate(I)

Cobalt(II), nickel(II) and copper(II) complexes of iso­quinoline-3-carbox­ylate

A dinuclear Co^II complex: bis­(μ-di­hydrogen phosphato-κ²O:O′)­bis­[(bi­pyridine-κ²N,N′)(di­hydrogen phosphato-κO)­cobalt(II)]

Poly­[[[(1,10-phenanthroline-κ²N,N′)­zinc(II)]-μ₃-5-hy­droxy­isophthalato-κ⁴O,O′:O′′:O′′′] monohydrate]

Di­chloro­(norborna­diene)­platinum(II): a comparison with di­chloro­(cyclo­octa­diene)­platinum(II)

{[Ba₂(C₂O₄)(H₂O)₆](NCS)₂}_n: a layered mixed-anion barium oxalate

A fluoro­phenylboron-functionalized zirconium silsesquioxane complex

Hemi[hexa­aqua­magnesium(II)] (μ-2,6-bis­{[bis­(carboxyl­ato­methyl)­amino]­methyl}-4-chloro­phenolato)­bis­[di­aqua­magnesium(II)] decahydrate

4,4,6,6-Tetra­chloro-2,2-(ethyl­ene­dioxydi-o-phenyl­enedi­imino)-2λ⁵,4λ⁵,6λ⁵-cyclo­triphosphazene

1-[(4-Chloro­benzoyl)­methyl]-4-(N,N-di­methyl­amino)­pyridinium bromide sesquihydrate and 1-[(4-bromo­benzoyl)­methyl]-4-(N,N-di­methyl­amino)­pyridinium bromide sesquihydrate

3,6-Di­hydroxy-2-(11-phenyl­undecan­oyl)­cyclo­hex-2-en-1-one from Virola venosa bark

2-Amino­pyridinium–fumarate–fumaric acid (2/1/1)

A new photochromic tetra­hydro­indolizine

Partially oxidized {2-[(benzoyl­methyl­ene)­diphenyl-λ⁵-phosphino]­ethyl}di­phenyl­phosphine as a monohydrate

3-tert-Butyl-7,7-di­methyl-1-phenyl-5,6,7,8-tetra­hydro­imidazo­[3,4-b]­quinolin-5-one and 2,8,8-tri­methyl-5-phenyl-6,7,8,9-tetra­hydroimidazo­[2,3-a]­quinolin-6-one: chains generated by C—H⋯N hydrogen bonds

S-Ethyl N-benzoyl­dithio­carbamate: two independent hydrogen-bonded R(8) dimers of different symmetry linked into chains by a C—H⋯π(arene) interaction

rac-3-(5-Amino-3-methyl-1-phenyl-1H-pyrazol-4-yl)-2-phenyl­thia­zolidin-4-one: sheets built from N—H⋯N and C—H⋯π(arene) hydrogen bonds

7-De­aza-2′-de­oxy-7-propynyl­guanosine

2-Benzoyl-N-phenyl-2-(1,2,4-triazol-1-yl)­thio­acet­amide and 2-(4-meth­oxy­benzoyl)-N-phenyl-2-(1,2,4-triazol-1-yl)­thio­acet­amide

(R)-4-(4-Fluoro­phenyl)-1-[2-hy­droxy-2-(3-methyl-1-benzo­furan-2-yl)­ethyl]­piperazinium chloride propan-1-ol solvate

5-Benzoyl­amino-3-bromo-4-(4-meth­oxy­phenyl)-4,5-di­hydro­isoxazole-5-carboxylic acid

2,6-Di­methyl-4-(phenyl­diazenyl)­phenol

2′-Amino-3-meth­oxy­pyrimidino­[5′,4′:16,17]­estra-1,3,5(10),16-tetra­ene­

rac-Eudesm-7(11)-en-4-ol

3-Bromo­methyl-3-ethyl-3,4,6,7,8,8a-hexa­hydro-1H-pyrrolo­[2,1-c][1,4]­oxazine-1,4-dione

N,N′-Bis­[1-(pyrazin-2-yl)­ethyl­idene]­hydrazine

(Benzo­furan-2-yl)(3-methyl-3-phenyl­cyclo­butyl)­methanone

N-(4-Fluoro­phenyl)-4-nitro­phthal­imide: tripartite hydrogen-bonded sheets

2,6-Di­benzyl-1,2,3,5,6,7-hexa­hydro-2,4,6,8-tetra­aza-s-indacene and 2,6-bis­(4-meth­oxy­benzyl)-1,2,3,5,6,7-hexa­hydro-2,4,6,8-tetra­aza-s-indacene

Ethyl (E)-3-(2-hy­droxy­phenyl)-2-(morpholino­carbonyl)­propenoate

Difur­aza­no[3,4-b:3′,4′-f]-4,5-di­aza-1,8-dioxa­cyclo­dodecine and an acyclic analogue

1,2-Bis­(methylsulfanyl)-1,2-dicarba-closo-dodecaborane(12)

Conformational switching caused by bi­phenyl substitution at the C^α position: ethyl 2-benzyl-2-(formyl­amino)-3-phenyl­propionate and ethyl 3-(1,1′-bi­phenyl-4-yl)-2-(formyl­amino)-2-(4-phenyl­benzyl)­propionate

Tri­phenyl­phosphine oxide–1-naphthoic acid (1/1)

(5,11,17,23-Tetra-tert-butyl-26,28-di­hydroxy­calix­[4]­arene-25,27-di­oxy)­diacetic acid N,N-di­methyl­form­amide tris­olvate

1-Chloro-3,6-di­meth­oxy-2,5-di­methyl­benzene and 1-chloro-3,6-di­meth­oxy-2,4-di­methyl­benzene