issue contents

Journal logoSTRUCTURAL
CHEMISTRY
ISSN: 2053-2296

December 2004 issue

Highlighted illustration

Cover illustration: A packing diagram for 3-bromo­pyridinium tri­bromo­acetate, illustrating the layer structure formed via classical hydrogen bonds, C-H...O interactions and Br...Br contacts (all shown as dashed lines), viewed perpendicular to (102). H atoms not involved in hydrogen bonds have been omitted for clarity. See Jones & Lozano [Acta Cryst. (2004), C60, o876-o878].

inorganic compounds


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In the structure of K2[HCr2AsO10], hydrogen bonds of 2.555 (5) Å between terminal O atoms of shared AsO3OH tetrahedra connect HCr2AsO102− ions. The displacement of the hydrogen-bonded O atoms by 0.586 Å in the predicted transition between phases II and I is larger than that of any other atom.

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The title compound was obtained by the reaction of Dy2O3 and B2O3 under conditions of high temperature and pressure (3 GPa and 1323 K) using a Walker-type multi-anvil assembly. Its crystal structure has been determined by single-crystal X-ray diffraction.

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A single-crystal synchrotron X-ray study of gadolinium aluminate, GdAlO3, revealed a perovskite-type structure with a common orthorhombic Pnma distortion, which has been discussed in association with the characteristic short Gd—Al—Gd linkage.

metal-organic compounds





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In the title compound, the decavanadate anions are surrounded by [Na2(H2O)10]2+ dications, forming layers, and diethyl­ene­di­ammonium cations are located between these layers.


















organic compounds



















Special and virtual issues

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Acta Crystallographica Section C is planning special issues on

The Structural Chemistry of Homogeneous and Heterogeneous Catalysts

NMR Crystallography.

Full details are available on the special issues page.

The latest virtual issue, featuring Coordination polymers and with an introduction by Len Barbour, was published in July 2014.

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