Synthesis and crystal structure of (2E)-1-[3,5-bis­(benz­yloxy)phen­yl]-3-(4-eth­oxy­phen­yl)prop-2-en-1-one

In the title compound, the phenyl rings of the chalcone unit subtend a dihedral angle of 26.43 (10)°. The phenyl rings of the pendant benz­yloxy groups are orientated at 75.57 (13) and 75.70 (10)° with respect to their attached ring. In the crystal, weak C—H⋯O and C—H⋯π inter­actions link the mol­ecules, forming C(15) chains propagating along [101].

Crystal structure of hexa­glycinium dodeca­iodo­triplumbate

The crystal structure of (GlyH)₆(Pb₃I₁₂) is reported. Dimeric cations of type (A⁺⋯A⁺) for the amino acid glycine are observed for the first time.

[SnF(bipy)(H₂O)]₂[SnF₆], a mixed-valent inorganic tin(II)–tin(IV) compound

The title compound represents a ionic mixed-valent tin(II)–tin(IV) compound with the bivalent tin atom as central atom of the cation and the tetra­valent tin atom as central atom of the anion. Regarding the first and second coordination sphere, the bivalent tin atom is fourfold, seesaw and fivefold, trapezoid–pyramidal coordinated while the tetra­valent tin atom exhibits an octa­hedral coordination.

Synthesis, crystal structure and Hirshfeld surface of ethyl 2-[2-(methyl­sulfan­yl)-5-oxo-4,4-di­phenyl-4,5-di­hydro-1H-imidazol-1-yl]acetate (thio­phenytoin derivative)

The di­hydro­imidazole ring in the title mol­ecule is slightly distorted and the lone pair on the tri-coordinate nitro­gen atom is involved in intra-ring π bonding. In the crystal, C—H⋯O hydrogen bonds form inversion dimers, which are connected along the a- and c-axis directions by additional C—H⋯O hydrogen bonds, forming layers parallel to the ac plane.

Crystal structure of bis­(β-alaninium) tetra­bromidoplumbate

This work focused on characterizing the structure from a stereochemical point of view, discussing the Pb^II character. The XRD data were collected at 200 K.

Synthesis, crystal structure and Hirshfeld surface analysis of 1-[(1-octyl-1H-1,2,3-triazol-4-yl)methyl]-3-phenyl-1,2-di­hydro­quinoxalin-2(1H)-one

The di­hydro­quinoxaline unit in the title mol­ecule is not quite planar and the mol­ecule adopts a hairpin conformation due in part to an intra­molecular C—H⋯O hydrogen bond. In the crystal, the polar portions of the mol­ecules are associated through C—H⋯O and C—H⋯N hydrogen bonds and C—H⋯π(ring) and C= O⋯π(ring) inter­actions, forming thick layers parallel to the bc plane and with the n-octyl groups on the outside surfaces.

Puckering effects of 4-hy­droxy-L-proline isomers on the conformation of ornithine-free Gramicidin S

The structures of Orn-free Gramicidin S with cis/trans-isomers of Hyp were solved, and the puckering of Hyp was unexpectedly down in both isomers.

Synthesis and crystal structure of 1,3-bis­(acet­oxymeth­yl)-5-{[(4,6-di­methyl­pyridin-2-yl)amino]­methyl}-2,4,6-tri­ethyl­benzene

In the crystal structure of the title compound, C₂₆H₃₆N₂O₄, the tripodal mol­ecule adopts a conformation in which the substituents attached to the central benzene ring are arranged in an alternating order above and below the ring plane.

Crystal structure of (1,4,7,10,13,16-hexa­oxa­cycloocta­decane-κ⁶O)potassium-μ-oxalato-tri­phenylstannate(IV), the first reported 18-crown-6-stabilized potassium salt of tri­phenyl­oxalatostannate

The single-crystal X-ray structure of [(18-crown-6)K][SnPh₃(ox)] (ox = C₂O₄²⁻) is reported. Integrity between neighboring mol­ecules in the solid state is maintained by an array of C—H⋯O hydrogen bonds and C—H⋯π inter­actions.

Crystal structure and Hirshfeld surface analysis of di­chlorido­[2-(3-cyclo­pentyl-1,2,4-triazol-5-yl-κN⁴)pyridine-κN]palladium(II) di­methyl­formamide monosolvate

The crystal structure of mononuclear di­chlorido­palladium(II) complex with 2-(3-cyclo­pentyl-1,2,4-triazol-5-yl)pyridine is reported and discussed.

Synthesis, crystal structure and Hirshfeld surface analysis of [Cu(H₂L)₂(μ-Cl)CuCl₃]·H₂O [H₂L = 2-hy­droxy-N′-(propan-2-yl­idene)benzohydrazide]

The synthesis and structural characterization of a dinuclear Cu^II complex, [tri­chlorido­copper(II)]-μ-chlorido-{bis­[2-hy­droxy-N′-(propan-2-yl­idene)benzohydrazide]copper(II)} monohydrate, [Cu₂Cl₄(C₁₀H₁₂N₂O₂)₂]·H₂O or [Cu(H₂L)₂(μ-Cl)CuCl₃]·H₂O is reported

Crystal structure and Hirshfeld surface analysis of 1-[6-bromo-2-(3-bromo­phen­yl)-1,2,3,4-tetra­hydro­quinolin-4-yl]pyrrolidin-2-one

In the crystal, mol­ecules are linked by inter­molecular N—H⋯O, C—H⋯O and C—H⋯Br hydrogen bonds, forming a three-dimensional network. In addition, pairs of mol­ecules along the c axis are connected by C—H⋯π inter­actions.

Crystal structure of propane-1,3-diaminium squarate dihydrate

The crystal structure of propane-1,3-diaminium squarate dihydrate (space group P4bm, Z = 2) features a triperiodic N—H⋯O and O—H⋯O hydrogen-bond network with a polar c axis.

Synthesis, crystal structure and Hirshfeld surface analysis of a new copper(II) complex based on di­ethyl 2,2′-(4H-1,2,4-triazole-3,5-di­yl)di­acetate

The synthesis and crystal structure of a new dinuclear copper(II) complex based on ethyl 2,2′-(1H-1,2,4-triazole-3,5-di­yl)-di­acetate is reported. Additionally, the results of a Hirshfeld surface analysis of [Cu₂(C₆H₅N₃O₄)₂(H₂O)₄]·2H₂O are described.

Crystal structure, Hirshfeld surface analysis, DFT and the mol­ecular docking studies of 3-(2-chloro­acet­yl)-2,4,6,8-tetra­phenyl-3,7-di­azabi­cyclo­[3.3.1]nonan-9-one

In the bicyclic title compound, C₃₃H₂₉ClN₂O₂, the two piperidine rings of the di­aza­bicylco moiety adopt distorted-chair conformations.

Three-dimensional alkaline earth metal–organic framework poly[[μ-aqua-aqua­bis­(μ₃-carba­moyl­cyano­nitro­somethanido)barium] monohydrate] and its thermal decomposition

A new alkaline earth metal three-dimensional polar MOF structure in barium carbamoyl­cyano­nitro­somethanide is governed by bridging coordination of the nitroso- and aqua O-atoms, which support a face-sharing connection of coordination polyhedra.

Crystal structure of a tris­(2-amino­eth­yl)methane capped carbamoyl­methyl­phosphine oxide compound

The crystal structure of the compound described here features both C—H⋯O and N—H⋯O intra­molecular hydrogen bonds, as well as a myriad of inter­molecular C—H⋯O hydrogen-bonding inter­actions.